MEASUREMENT OF VIBRATIONAL CIRCULAR DICHROISM BELOW 600 CM-1 : PROGRESS TOWARDS MEETING THE CHALLENGE
作者： Prasad L. Polavarapu , Zhengyu Deng
关键词: Circular dichroism 、 Chemistry 、 Circular polarization 、 Beam splitter 、 Optics 、 Vibrational circular dichroism 、 Polarization (waves) 、 Interferometry 、 Far infrared
摘要: The measurement of vibrational circular dichroism (VCD) below ∼600 cm-1 is one the experimental challenges current times. Polarization-division interferometry considered to be most efficient approach for realizing these measurements. A crucial component successful applications this beamsplitter, which divides incoming beam according polarization. Free-standing metal wires and deposited on a mylar substrate have been employed as beamsplitters, their performance has evaluated ∼700-10 region. VCD measurements obtained enantiomers α-pinene in 400-250 region are presented. status future developments needed routine far-infrared summarized.
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