Electrochemical reaction of lithium with CoP3
作者： R Alcantara , JL Tirado , JC Jumas , L Monconduit , J Olivier-Fourcade
DOI: 10.1016/S0378-7753(02)00081-2
关键词: X-ray absorption spectroscopy 、 X-ray crystallography 、 Reversible process 、 Gravimetric analysis 、 Reaction mechanism 、 Physical chemistry 、 Electrochemistry 、 Nuclear chemistry 、 Chemistry 、 Cobalt 、 Lithium
摘要: Abstract The electrochemical reaction of lithium with the skutterudite-type CoP3 compound has been studied. To follow mechanism, X-ray diffraction (XRD), 7 Li nuclear magnetic resonance (NMR) and absorption (XAS) experiments have carried out. During first phase, cobalt is reduced lithium-phosphide formed. reversible process observed during subsequent cycles consists formation Li3P from its elements, giving a maximum in gravimetric capacity 487 mAh/g.
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