The low‐temperature thermal conductivity of a polyoxymethylene ’’crystal’’

作者: D. Greig , R. Jakeways , M. Sahota

DOI: 10.1063/1.435788

关键词: Composite materialPolymerSingle crystalPolyoxymethyleneAtmospheric temperature rangeThermal conductivityMaterials scienceCrystalConductivityFiberPhysical and Theoretical ChemistryGeneral Physics and Astronomy

摘要: The thermal conductivity κ of a polyoxymethylene (POM) ’’crystal’’ has been measured both parallel and perpendicular to the direction fibers between 1.5 100 K. In fiber κ∥ is very much less than might be expected from single crystal but instead similar throughout temperature range extruded POM. Perpendicular κ⊥ rather in material, particularly at lowest temperatures where, even for polymers, unusually small. These observations lead deductions about specimen morphology that are substantiated by experiments involving x‐ray diffraction.

参考文章(10)
G. K. White, T. F. Smith, J. A. Birch, Thermal expansion and Grüneisen parameters of a polyoxymethylene crystal Journal of Chemical Physics. ,vol. 65, pp. 554- 558 ,(1976) , 10.1063/1.433135
S Burgess, D Greig, The low-temperature thermal conductivity of polyethylene Journal of Physics C: Solid State Physics. ,vol. 8, pp. 1637- 1648 ,(1975) , 10.1088/0022-3719/8/11/015
A. G. Gibson, D. Greig, M. Sahota, I. M. Ward, C. L. Choy, Thermal conductivity of ultrahigh-modulus polyethylene Journal of Polymer Science: Polymer Letters Edition. ,vol. 15, pp. 183- 192 ,(1977) , 10.1002/POL.1977.130150401
C L Choy, D Greig, The low-temperature thermal conductivity of a semi-crystalline polymer, polyethylene terephthalate Journal of Physics C: Solid State Physics. ,vol. 8, pp. 3121- 3130 ,(1975) , 10.1088/0022-3719/8/19/012
Gian Alvisé Carazzolo, Structure of the normal crystal form of polyoxymethylene Journal of Polymer Science Part A: General Papers. ,vol. 1, pp. 1573- 1583 ,(1963) , 10.1002/POL.1963.100010510
A. C. Anderson, R. B. Rauch, Low‐Temperature Thermal Conductivity of a Suspension of Copper Particles Journal of Applied Physics. ,vol. 41, pp. 3648- 3651 ,(1970) , 10.1063/1.1659486
A. E. Stephens, H. J. Mackey, J. R. Sybert, Effects of Contact Placement and Sample Shape in the Measurement of Electrical Resistivity Journal of Applied Physics. ,vol. 42, pp. 2592- 2597 ,(1971) , 10.1063/1.1660594
W. A. Phillips, Phonon Scattering in Polyethylene at Low Temperatures Physical Review B. ,vol. 3, pp. 4338- 4341 ,(1971) , 10.1103/PHYSREVB.3.4338
C L Choy, D Greig, The low temperature thermal conductivity of isotropic and oriented polymers Journal of Physics C: Solid State Physics. ,vol. 10, pp. 169- 179 ,(1977) , 10.1088/0022-3719/10/2/005
S Burgess, D Greig, The low-temperature thermal conductivity of two-phase amorphous polymers Journal of Physics D. ,vol. 7, pp. 2051- 2057 ,(1974) , 10.1088/0022-3727/7/15/309