Methylation of amines, nitrobenzenes and aromatic nitriles with carbon dioxide and molecular hydrogen
作者： Xinjiang Cui , Xingchao Dai , Yan Zhang , Youquan Deng , Feng Shi
DOI: 10.1039/C3SC52676C
关键词: Alkylation 、 Carbon dioxide 、 Nitrile 、 Methylation 、 Chemistry 、 Nitrobenzene 、 Catalysis 、 Organic chemistry 、 Hydrogen molecule 、 Amine gas treating
摘要: CO2/H2 was successfully employed in alkylation reactions by performing CO2 reduction and amine N-methylation one-pot. In the presence of a simple CuAlOx catalyst, N-methyl or N,N-dimethyl amines with different structures can be selectively synthesized up to 96% yields applying amine, nitrobenzene nitrile as starting materials.
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