Characterization of Trace Amounts of Odorants (Sulfur Compounds, Oxygenates, Hydrocarbons, Phenols and Lower Fatty Acids) in Air in an ICU Room

作者: Yasuyuki HOSHIKA

DOI: 10.1265/JJH.48.733

关键词: EthanolOdorChemistryAcetaldehydeGas chromatographySulfurTrace AmountsPhenolsChromatographyEnvironmental chemistryOxygenate

摘要: Characterization of trace amounts odorants in air an ICU room (ca. 257m2) was carried out by gas chromatography and atmospheric pressure ionization-mass spectrometry (API-MS). The concentrations odor recognition threshold values the detected odorants, acetaldehyde, ethanol, n-butyric acid, iso-valeric acid n-valeric are as follows: 44.7ppb 15ppb; 19710ppb 6100ppb; 0.50ppb 0.4ppb; 0.45ppb 0.67ppb 0.5ppb, respectively. these were significantly higher than values. compounds may, therefore, be responsible for perception such odors mixed odors, body odor, faint or recognizable alcoholic disinfectant sour, pungent, goaty odors.

参考文章(17)
D. I. Carroll, I. Dzidic, R. N. Stillwell, M. G. Horning, E. C. Horning, Subpicogram detection system for gas phase analysis based upon atmospheric pressure ionization (API) mass spectrometry Analytical Chemistry. ,vol. 46, pp. 706- 710 ,(1974) , 10.1021/AC60342A009
Yasuyuki Hoshika, Yoshinori Takata, Gas Chromatographic Separation of Carbonyl Compounds as Their 2,4-dinitrophenylhydrazones Using Glass Capillary Columns Journal of Chromatography A. ,vol. 120, pp. 379- 389 ,(1976) , 10.1016/S0021-9673(76)80015-5
Gregory Leonardos, David Kendall, Nancy Barnard, Odor Threshold Determinations of 53 Odorant Chemicals Journal of the Air Pollution Control Association. ,vol. 19, pp. 91- 95 ,(1969) , 10.1080/00022470.1969.10466465
Jan. Sunner, Michael G. Ikonomou, Paul. Kebarle, Sensitivity enhancements obtained at high temperatures in atmospheric pressure ionization mass spectrometry Analytical Chemistry. ,vol. 60, pp. 1308- 1313 ,(1988) , 10.1021/AC00164A013
E. C. Horning, M. G. Horning, D. I. Carroll, I. Dzidic, R. N. Stillwell, New picogram detection system based on a mass spectrometer with an external ionization source at atmospheric pressure Analytical Chemistry. ,vol. 45, pp. 936- 943 ,(1973) , 10.1021/AC60328A035
Hideki. Kambara, Ichiro. Kanomata, Determination of impurities in gases by atmospheric pressure ionization mass spectrometry Analytical Chemistry. ,vol. 49, pp. 270- 275 ,(1977) , 10.1021/AC50010A023
Yasuyuki Hoshika, Glichi Muto, Gas—liquid—solid chromatographic determination of phenols in air using Tenax-GC and alkaline precolumns Journal of Chromatography A. ,vol. 157, pp. 277- 284 ,(1978) , 10.1016/S0021-9673(00)92343-4