HIGH-PRESSURE LOW-TEMPERATURE PHASE TRANSITION IN A DOPED PARA-TERPHENYL CRYSTAL : A SPECTRAL-HOLE-BURNING STUDY

作者: Jaak Kikas , Arlentin Laisaar , Artur Suisalu , Anatoli Kuznetsov , Aleksandr Ellervee

DOI: 10.1103/PHYSREVB.57.14

关键词: Condensed matter physicsHydrostatic equilibriumPhase transitionDopingSpectral hole burningTerphenylThermalActivation energyMaterials scienceCrystal

摘要: The homogeneous width of zero-phonon lines in a chlorin-doped para-terphenyl crystal is determined by spectral hole burning at $T=4.2--14\mathrm{K}$ under various hydrostatic pressures up to 7 kbar. A drastic broadening holes with pressure occurs on approaching the order-disorder (triclinic-to-monoclinic) phase transition which takes place $P\ensuremath{\approx}5.5\mathrm{kbar}$ $4.2l~Tl~14\mathrm{K}.$ thermal fixed an activated process activation energy depending and having deep minimum $P\ensuremath{\approx}5.5\mathrm{kbar},$ i.e., phase-transition region.

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