Combined Triple and Double Bonds to Uranium: The N≡U═N−H Uranimine Nitride Molecule Prepared in Solid Argon

作者: Xuefeng Wang , Lester Andrews , Bess Vlaisavljevich , Laura Gagliardi

DOI: 10.1021/IC2003244

关键词: Double bondUraniumPhysical chemistryChemistryInorganic chemistryNitrideMoleculeArgonInfrared

摘要: Reactions of laser-ablated U atoms with N2 and H2 mixtures upon codeposition in excess argon at 5 K gave strong NUN weak UN infrared absorptions new bands 3349.7, 966.9, 752.4, 433.0...

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