Process for producing polyamines

作者: Susumu Harada , Kiyoshi Shimizu

DOI:

关键词: MorpholineHydroquinoneBenzophenoneMaleic anhydrideOrganic chemistryChemistryAcetophenoneMaleic acidPolymerizationPolymer chemistryAlkyl

摘要: Polymers or copolymers of diallylamine derivatives the formula, CH2=CR1-CH2+R2 ANGLE N CH2=CR1-CH2R3 Y wherein R1 is hydrogen methyl: R2 and R3 are independently hydrogen, allyl, methallyl, straight-chain branched-chain alkyl having 1-16 carbon atoms, phenylalkyl hydroxyalkyl HO-(-CH2-)m-, in which m ia an integer 1-6 may form together with adjacent atom pyrrolidyl, piperidyl morpholino; halogen inorganic acid anion, produced by conducting photopolymerization a solution slurry at least one derivative mentioned above without other comonomer such as maleic anhydride, acid, vinyl compound, irradiation light wavelengths 150-500 mu . The polymerization rate can be accelerated presence special sensitizer benzophenone acetophenone hydroquinone, dioxane, morpholine thereof, charge-transfer complex sulfur dioxide derivative.