Functional separator with VGCF/PPY coating for high cyclic stability lithium–sulfur battery
作者： Jianna Deng , Jianqiang Guo , Jing Li , Min Zeng , Zhou Yang
DOI: 10.1016/J.MATLET.2018.09.059
关键词: Conductivity 、 Chemical engineering 、 Polypyrrole 、 Lithium–sulfur battery 、 Dissolution 、 Coating 、 Polysulfide 、 Electrode 、 Separator (electricity) 、 Materials science
摘要: Abstract Repeated dissolution and deposition of polysulfide during the cycle could lead to a non-conductive layer on cathode electrode, which would cause decrease conductivity for positive electrode limit effect sulfur-based conductive material. Therefore, we proposed vapor growth carbon fiber/polypyrrole (VGCF/PPY) dual functional separator, can increase by VGCF absorb PPY. Finally, VGCF/PPY separator displays an initial discharge specific capacity 1085 mAh g−1 at 0.1 C. The remains 768 mAh g−1 after 200 cycles with decay 0.146% per cycle, showing excellent stability.
sci-hub.se 参考文章(12)
Yan Diao, Kai Xie, Shizhao Xiong, Xiaobin Hong, Shuttle phenomenon – The irreversible oxidation mechanism of sulfur active material in Li–S battery Journal of Power Sources. ,vol. 235, pp. 181- 186 ,(2013) , 10.1016/J.JPOWSOUR.2013.01.132
Gaind P. Pandey, Tao Liu, Cody Hancock, Yonghui Li, Xiuzhi Susan Sun, Jun Li, Thermostable gel polymer electrolyte based on succinonitrile and ionic liquid for high-performance solid-state supercapacitors Journal of Power Sources. ,vol. 328, pp. 510- 519 ,(2016) , 10.1016/J.JPOWSOUR.2016.08.032
Hong-Jie Peng, Ze-Wen Zhang, Jia-Qi Huang, Ge Zhang, Jin Xie, Wen-Tao Xu, Jia-Le Shi, Xiang Chen, Xin-Bing Cheng, Qiang Zhang, A Cooperative Interface for Highly Efficient Lithium–Sulfur Batteries Advanced Materials. ,vol. 28, pp. 9551- 9558 ,(2016) , 10.1002/ADMA.201603401
Shiqi Li, Guofeng Ren, Md Nadim Ferdous Hoque, Zhihua Dong, Juliusz Warzywoda, Zhaoyang Fan, Carbonized cellulose paper as an effective interlayer in lithium-sulfur batteries Applied Surface Science. ,vol. 396, pp. 637- 643 ,(2017) , 10.1016/J.APSUSC.2016.10.208
Tao Li, Yan Yuan, Bo Hong, Huawei Cao, Kai Zhang, Yanqing Lai, Yexiang Liu, Zixin Huang, Hybrid polyacrylamide/carbon coating on sulfur cathode for advanced lithium sulfur battery Electrochimica Acta. ,vol. 244, pp. 192- 198 ,(2017) , 10.1016/J.ELECTACTA.2017.05.081
Dong Kyu Lee, Chi Won Ahn, Hwan-Jin Jeon, Web-structured graphitic carbon fiber felt as an interlayer for rechargeable lithium-sulfur batteries with highly improved cycling performance Journal of Power Sources. ,vol. 360, pp. 559- 568 ,(2017) , 10.1016/J.JPOWSOUR.2017.06.048
Haipeng Li, Liancheng Sun, Yongguang Zhang, Taizhe Tan, Gongkai Wang, Zhumabay Bakenov, Enhanced cycle performance of Li/S battery with the reduced graphene oxide/activated carbon functional interlayer Journal of Energy Chemistry. ,vol. 26, pp. 1276- 1281 ,(2017) , 10.1016/J.JECHEM.2017.09.009
Zhirong Sun, Ge Song, Ran Du, Xiang Hu, Modification of a Pd-loaded electrode with a carbon nanotubes–polypyrrole interlayer and its dechlorination performance for 2,3-dichlorophenol RSC Advances. ,vol. 7, pp. 22054- 22062 ,(2017) , 10.1039/C7RA02515G
Jing Li, Jianqiang Guo, Li Zeng, Yeju Huang, Rufang Peng, Improving lithium–sulfur battery performance by using ternary hybrid cathode material RSC Advances. ,vol. 6, pp. 26630- 26636 ,(2016) , 10.1039/C6RA01722C
Hongbin Yao, Kai Yan, Weiyang Li, Guangyuan Zheng, Desheng Kong, Zhi Wei Seh, Vijay Kris Narasimhan, Zheng Liang, Yi Cui, Improved lithium–sulfur batteries with a conductive coating on the separator to prevent the accumulation of inactive S-related species at the cathode–separator interface Energy and Environmental Science. ,vol. 7, pp. 3381- 3390 ,(2014) , 10.1039/C4EE01377H