1-D networks formed by metal⋯sulfur van der Walls contacts: Novel tetrazole–thiolato Pd(II) and Pt(II) complexes
作者： Hyeong-Tak Jeon , Kyung-Eun Lee , Yong-Joo Kim , Soon W. Lee
DOI: 10.1016/J.INOCHE.2009.09.030
关键词: Pyridine 、 Crystallography 、 van der Waals force 、 Stereochemistry 、 Aryl 、 Sulfur 、 Intermolecular force 、 Isothiocyanate 、 Chemistry 、 Metal 、 Tetrazole
摘要: Abstract Pd(II)– and Pt(II)–azido complexes, [M(N3)(PMe3)2(C–L)] {LH = 2-(2′)-thienyl pyridine; M = Pd (1), Pt(2)}, which contain σ-bonded heterocycles (L), were treated with aryl isothiocyanate (Me2C6H3–NCS) to afford the corresponding Pd(II) Pt(II) tetrazole–thiolato trans-{M[SCN4(2,6-Me2C6H3)](PMe3)2(C–L)} {M = Pd (3), Pt (4)}. Complexes 3 4 have a 1-D helical network formed by intermolecular M⋯S van der Waals contacts.
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