Hydrogen Desorption from the NaNH2−MgH2 System
作者： Drew A. Sheppard , Mark Paskevicius , Craig E. Buckley
DOI: 10.1021/JP200242W
关键词: Sodium amide 、 Magnesium hydride 、 Imide 、 Thermal desorption spectroscopy 、 Fourier transform infrared spectroscopy 、 Desorption 、 Hydrogen 、 Inorganic chemistry 、 Nitride 、 Chemistry 、 Analytical chemistry
摘要: Ball-milled sodium amide and magnesium hydride (NaNH2:MgH2 = 1:1 molar ratio) desorbs 3.3 wt % of hydrogen between 70 335 °C with three desorption events. X-ray diffraction indicates that the is associated two unidentified magnesium-containing phases. Fourier transform infrared spectroscopy these phases correspond to an imide nitride, respectively. Analysis products shows a large excess NaH MgH2 optimizing starting reagents will increase both kinetics amount desorbed from system below 165 °C.
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