Molluscicidal saponins of Phytolacca dodecanra: Oleanoglycotoxin-A

作者: Robert M. Parkhurst , David W. Thomas , Wilfred A. Skinner , Lewis W. Cary

DOI: 10.1016/0031-9422(73)80580-1

关键词: Combined useOleanolic acidChemistryStereochemistryGlycosideMolluscicidePhytolaccaPhytolaccaceaePhytolacca dodecandra

摘要: Abstract The structure of one the major molluscicidal saponins fruit Phytolacca dodecandra has been elucidated as 3-[2,4-di-O-(β- d- glucopyranosyl)-β- d -glucopyranosyll-olean-12-ene-28-oic acid. combined use 300 Mc. PMR, MS and GC-MS led to this structural assignment.

参考文章(6)
Aklilu Lemma, Laboratory and field evaluation of the molluscicidal properties of Phytolacca dodecandra. Bulletin of The World Health Organization. ,vol. 42, pp. 597- 612 ,(1970)
J.W. Powell, W.B. Whalley, Triterpenoid saponins from Phytolacca dodecandra Phytochemistry. ,vol. 8, pp. 2105- 2107 ,(1969) , 10.1016/S0031-9422(00)88105-4
J.S. Brimacombe, B.D. Jones, M. Stacey, J.J. Willard, Alkylation of carbohydrates using sodium hydride Carbohydrate Research. ,vol. 2, pp. 167- 169 ,(1966) , 10.1016/S0008-6215(00)81480-9
Aklilu Lemma, Gerald Brody, Gordon W. Newell, R. M. Parkhurst, W. A. Skinner, Studies on the molluscicidal properties of endod (Phytolacca dodecandra). I. Increased potency with butanol extraction. Journal of Parasitology. ,vol. 58, pp. 104- 107 ,(1972) , 10.2307/3278251
C. C. Sweeley, Ronald Bentley, M. Makita, W. W. Wells, Gas-Liquid Chromatography of Trimethylsilyl Derivatives of Sugars and Related Substances American Chemical Society. ,(2002) , 10.1021/JA00899A032