11 DFT and experimental studies of C-C and C-O bond cleavage in ethanol and ethylene glycol on Pt catalysts

作者: R.R. Davda , R. Alcalá , J. Shabaker , G. Huber , R.D. Cortright

DOI: 10.1016/S0167-2991(03)80168-4

关键词: HydrogenAlkaneEthylene glycolCatalysisMedicinal chemistryTransition stateChemistryPhotochemistryBond cleavageDehydrogenationChemical kinetics

摘要: … to selectively cleave CC bonds in oxygenated hydrocarbons, … ethylene glycol, at relatively low temperatures (eg, 500 K). Moreover, we show that this catalytic reaction of ethylene glycol …

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