Pressure-Induced Metal-Semiconductor Transition and4fElectron Delocalization in Sm Te

作者: A. Jayaraman , V. Narayanamurti , E. Bucher , R. G. Maines

DOI: 10.1103/PHYSREVLETT.25.368

关键词: Conduction bandMetal semiconductorCondensed matter physicsInfrared spectroscopyPhysicsElectronSaturation (graph theory)Absorption (logic)Electrical resistivity and conductivityElectron delocalization

摘要: The pressure variation of resistivity and optical absorption in SmTe has been studied. A continuous pressure-induced semiconductor-to-metal transition is observed, which we ascribe to the promotion electrons from $4f$ level into conduction band as gap between them shrinks with finally vanishes. deduced saturation ratio $\frac{\ensuremath{\rho}{(P)}_{\mathrm{sat}}}{\ensuremath{\rho}(0)}$ good agreement 0.62 \ifmmode\pm\else\textpm\fi{} 0.02 eV obtained infrared data.

参考文章(8)
F.J. Reid, L.K. Matson, J.F. Miller, R.C. Himes, Electrical conduction in rare-earth monoselenides and monotellurides and their alloys Journal of Physics and Chemistry of Solids. ,vol. 25, pp. 969- 976 ,(1964) , 10.1016/0022-3697(64)90034-4
R. Didchenko, F.P. Gortsema, Some electric and magnetic properties of rare earth monosulfides and nitrides Journal of Physics and Chemistry of Solids. ,vol. 24, pp. 863- 870 ,(1963) , 10.1016/0022-3697(63)90062-3
J. O. Dimmock, Optical Properties of the Europium Chalcogenides IBM Journal of Research and Development. ,vol. 14, pp. 301- 308 ,(1970) , 10.1147/RD.143.0301
P. Wachter, Pressure dependence of the absorption edge of the Europium-chalcogenides Solid State Communications. ,vol. 7, pp. 693- 696 ,(1969) , 10.1016/0038-1098(69)90595-X
M. R. Oliver, J. A. Kafalas, J. O. Dimmock, T. B. Reed, Pressure Dependence of the Electrical Resistivity of EuO Physical Review Letters. ,vol. 24, pp. 1064- 1067 ,(1970) , 10.1103/PHYSREVLETT.24.1064
A. G. Foyt, R. E. Halsted, William Paul, Evidence for Impurity States Associated with High-Energy Conduction-Band Extrema inn-CdTeCdTe Physical Review Letters. ,vol. 16, pp. 55- 58 ,(1966) , 10.1103/PHYSREVLETT.16.55
B. B. Kosicki, W. Paul, A. J. Strauss, G. W. Iseler, Sulfur Donor Level Associated with (100) Conduction Band of GaSb Physical Review Letters. ,vol. 17, pp. 1175- 1177 ,(1966) , 10.1103/PHYSREVLETT.17.1175
L. M. Falicov, J. C. Kimball, Simple Model for Semiconductor-Metal Transitions: Sm B 6 and Transition-Metal Oxides Physical Review Letters. ,vol. 22, pp. 997- 999 ,(1969) , 10.1103/PHYSREVLETT.22.997