Rhombic Dodecahedral Ag8M6 (M = Cu, Ag, Au) Cluster Complexes of Ferrocenylethynyl Prepared by Reaction of (AgC⋮CFc)n with [M2(Ph2PNHPh2)2(MeCN)2]2+ (M = Cu, Ag, Au)
作者： Qiao-Hua Wei , Gang-Qiang Yin , Li-Yi Zhang , Zhong-Ning Chen
DOI: 10.1021/OM0607346
关键词: Dodecahedron 、 Crystallography 、 Cluster (physics) 、 Redox 、 Stereochemistry 、 Chemistry
摘要: Reaction of the polymeric silver ferrocenylacetylide (AgC⋮CFc)n with [M2(Ph2PNHPPh2)2(MeCN)2]2+ (M = Cu, Ag, Au) gave rise to isolation rhombic dodecahedral AgI8MI6 cage complexes together unusual 1,2,5-azadiphospholium product [FcCCH(Ph2PNPPh2)](BF4) by cyclic addition FcC⋮C Ph2PNHPPh2. Distinct redox wave splitting occurs in AgI8CuI6 complex ΔE1/2 0.15 V due successive oxidation Fc groups, induced probably electronic interactions between iron centers ferrocenylacetylides.
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sci-hub.se 参考文章(36)
John H. K. Yip, Jianguo Wu, Kwok-Yin Wong, Kin-Wai Yeung, Jagadese J. Vittal, Syntheses, Structures, and Electrochemistry of Polynuclear CuI, AgI, and PtII Complexes Bearing Ferrocenyl Group Organometallics. ,vol. 21, pp. 1612- 1621 ,(2002) , 10.1021/OM010998M
Michael C. B. Colbert, Jack Lewis, Nicholas J. Long, Paul R. Raithby, Andrew J. P. White, David J. Williams, Synthetic, structural, electrochemical and electronic characterisation of heterobimetallic bis(acetylide) ferrocene complexes Journal of The Chemical Society-dalton Transactions. pp. 99- 104 ,(1997) , 10.1039/A605177D
Guo-Lin Xu, Robert J. Crutchley, Maria C. DeRosa, Qing-Jiang Pan, Hong-Xing Zhang, Xiaoping Wang, Tong Ren, Strong Electronic Couplings between Ferrocenyl Centers Mediated by Bis-Ethynyl/Butadiynyl Diruthenium Bridges Journal of the American Chemical Society. ,vol. 127, pp. 13354- 13363 ,(2005) , 10.1021/JA0534452
Jochen Ellermann, J�rgen Utz, Falk A. Knoch, Matthias Moll, Chemie polyfunktioneller Moleküle. 124. Silber(I)-Komplexe mit den Liganden Bis(diphenylphosphanyl)amin, -amid und Tris(diphenylphosphanyl)amin† Zeitschrift für anorganische und allgemeine Chemie. ,vol. 622, pp. 1871- 1878 ,(1996) , 10.1002/ZAAC.19966221111
John F. Berry, F. Albert Cotton, Carlos A. Murillo, A Trinuclear EMAC-Type Molecular Wire with Redox-Active Ferrocenylacetylide “Alligator Clips” Attached Organometallics. ,vol. 23, pp. 2503- 2506 ,(2004) , 10.1021/OM049979D
Slawomir Szafert, J. A. Gladysz, Carbon in one dimension: structural analysis of the higher conjugated polyynes. Chemical Reviews. ,vol. 103, pp. 4175- 4205 ,(2003) , 10.1021/CR030041O
Guo-Lin Xu, Maria C. DeRosa, Robert J. Crutchley, Tong Ren, trans-Bis(alkynyl) diruthenium(III) tetra(amidinate): an effective facilitator of electronic delocalization. Journal of the American Chemical Society. ,vol. 126, pp. 3728- 3729 ,(2004) , 10.1021/JA049915U
Nicholas J. Long, Charlotte K. Williams, Metal Alkynyl σ Complexes: Synthesis and Materials Angewandte Chemie International Edition. ,vol. 42, pp. 2586- 2617 ,(2003) , 10.1002/ANIE.200200537
Qiao-Hua Wei, Gang-Qiang Yin, Li-Yi Zhang, Lin-Xi Shi, Zong-Wan Mao, Zhong-Ning Chen, Luminescent AgI−CuI Heterometallic Hexa-, Octa-, and Hexadecanuclear Alkynyl Complexes Inorganic Chemistry. ,vol. 43, pp. 3484- 3491 ,(2004) , 10.1021/IC0499244
Qiao-Hua Wei, Li-Yi Zhang, Lin-Xi Shi, Zhong-Ning Chen, Octahedral hexanuclear silver(I) and copper(I) ferrocenylacetylide complexes Inorganic Chemistry Communications. ,vol. 7, pp. 286- 288 ,(2004) , 10.1016/J.INOCHE.2003.11.026