Uniaxial Deformation of Nylon 6–Clay Nanocomposites by In-Situ Synchrotron X-Ray Measurements

作者: Francisco J. Medellin-Rodríguez , Benjamin S. Hsiao , Benjamin Chu , Bruce X. Fu

DOI: 10.1081/MB-120015759

关键词: Materials scienceCrystalliteMontmorilloniteDeformation (engineering)Composite materialUltimate tensile strengthNylon 6Young's modulusNanocompositeFilm plane

摘要: An in-situ uniaxial deformation study of nylon 6–clay hybrid (NCH) nanocomposites was carried out using simultaneous wide-angle x-ray diffraction (WAXD) and small-angle scattering (SAXS) techniques with synchrotron radiation. This nanocomposite system exhibited the partial exfoliated clay morphology. The WAXD patterns along through-and edge-views from as-pressed film samples indicated that both platelets 6 crystallites were parallel to plane but oriented randomly in plane. During deformation, orientation molecular axis crystals increased strain decreased content. behavior could be attributed rotation during which hindered crystals. corresponding tensile mechanical properties elongation at break modulus strength concentration, has been observed before.

参考文章(13)
E.M. Bradbury, L. Brown, A. Elliott, D.A.D. Parry, The structure of the gamma form of polycaproamide (Nylon 6) Polymer. ,vol. 6, pp. 465- 482 ,(1965) , 10.1016/0032-3861(65)90032-7
Arimitsu Usuki, Yoshitsugu Kojima, Masaya Kawasumi, Akane Okada, Yoshiaki Fukushima, Toshio Kurauchi, Osami Kamigaito, Synthesis of nylon 6-clay hybrid Journal of Materials Research. ,vol. 8, pp. 1179- 1184 ,(1993) , 10.1557/JMR.1993.1179
F. J. Medell�n-Rodr�guez, P. J. Phillips, J. S. Lin, C. A. Avila-Orta, Triple melting behavior of poly(ethylene terephthalate co‐1,4‐cyclohexylene dimethylene terephthalate) random copolyesters Journal of Polymer Science Part B. ,vol. 36, pp. 763- 781 ,(1998) , 10.1002/(SICI)1099-0488(19980415)36:5<763::AID-POLB4>3.0.CO;2-M
J. J. Hermans, P. H. Hermans, D. Vermaas, A. Weidinger, Quantitative evaluation of orientation in cellulose fibres from the X-ray fibre diagram Recueil des Travaux Chimiques des Pays-Bas. ,vol. 65, pp. 427- 447 ,(1946) , 10.1002/RECL.19460650605
Ramanan Krishnamoorti, Emmanuel P. Giannelis, Rheology of End-Tethered Polymer Layered Silicate Nanocomposites Macromolecules. ,vol. 30, pp. 4097- 4102 ,(1997) , 10.1021/MA960550A
Francisco J. Medellin-Rodriguez, Christian Burger, Benjamin S. Hsiao, Benjamin Chu, Richard Vaia, Shawn Phillips, Time-resolved shear behavior of end-tethered Nylon 6–clay nanocomposites followed by non-isothermal crystallization Polymer. ,vol. 42, pp. 9015- 9023 ,(2001) , 10.1016/S0032-3861(01)00395-0
Yoshitsugu Kojima, Arimitsu Usuki, Masaya Kawasumi, Akane Okada, Toshio Kurauchi, Osami Kamigaito, Keisuke Kaji, Novel preferred orientation in injection-molded nylon 6-clay hybrid Journal of Polymer Science Part B: Polymer Physics. ,vol. 33, pp. 1039- 1045 ,(1995) , 10.1002/POLB.1995.090330707
H. Arimoto, M. Ishibashi, M. Hirai, Y. Chatani, Crystal structure of the γ‐form of nylon 6 Journal of Polymer Science Part A. ,vol. 3, pp. 317- 326 ,(1965) , 10.1002/POL.1965.100030132
Yoshitsugu Kojima, Arimitsu Usuki, Masaya Kawasumi, Akane Okada, Yoshiaki Fukushima, Toshio Kurauchi, Osami Kamigaito, Mechanical properties of nylon 6-clay hybrid Journal of Materials Research. ,vol. 8, pp. 1185- 1189 ,(1993) , 10.1557/JMR.1993.1185