Assembly of an R3N52− Chain by Cycloaddition of a Hydrazinediide and an Azide at Zirconium and its Thermal Fragmentation
作者： Thorsten Gehrmann , Julio Lloret Fillol , Hubert Wadepohl , Lutz H. Gade
关键词: Azide 、 Cycloaddition 、 Medicinal chemistry 、 Zirconium 、 Chemistry 、 Photochemistry 、 Fragmentation (mass spectrometry)
摘要: Gesprengte Kette: Formale [2+3]-Cycloadditionen eines Zirconiumhydrazindiids mit organischen Aziden fuhren zu 2-Pentazen-1,4-diyl-Komplexen wie dem abgebildeten [Zr(N2TBSNpy){N(Ad)N3NPh2}] (C grau, N blau, Si grun, Zr turkis). Die Bindungsverhaltnisse in der N5-Kette wurden mithilfe von Dichtefunktionalrechnungen untersucht. Beim Erhitzen spalten die Komplexe N2 ab, und es resultieren side-on-gebundene Diazenide.
sci-hub.se 参考文章(63)
Ray Engelke, Ab initio correlated calculations of six nitrogen (N6) isomers The Journal of Physical Chemistry. ,vol. 96, pp. 10789- 10792 ,(1992) , 10.1021/J100205A037
Michael I. Bruce, Michael L. Williams, Brian W. Skelton, Allan H. White, Cluster chemistry ☆: XXXXVI. Some ruthenium carbonyl cluster complexes containing aryldiazo ligands: X-ray structure of Ru3(μ3-PPhCH2PPh2)(μ-η1-NNC6H3Cl2-2,4)(CO)9 Journal of Organometallic Chemistry. ,vol. 309, pp. 157- 168 ,(1986) , 10.1016/S0022-328X(00)99581-0
Philippe Schollhammer, Erwann Guénin, François Y. Pétillon, Jean Talarmin, Kenneth W. Muir, Dmitri S. Yufit, η1−η2 Rearrangement and Protonation of Phenyldiazo Bridging Ligands Attached to the Dimolybdenum System {Mo2Cp2(μ-SMe)3} Organometallics. ,vol. 17, pp. 1922- 1924 ,(1998) , 10.1021/OM971114V
Johannes Beck, Joachim Strähle, Synthese und Kristallstruktur von Bis[1,5-ditolylpentaazadienido-thallium(I)] und Bis[1,3-diphenyltriazenido-thallium(I)]/Synthesis and Crystal Structure of Bis[1,5-Ditolylpentaazadienido-thallium(I)] and Bis[ 1,3-diphenyltriazenido-thallium(I)] Zeitschrift für Naturforschung B. ,vol. 41, pp. 1381- 1386 ,(1986) , 10.1515/ZNB-1986-1111
Geoffrey Wilkinson, None, Reactions of iridium and ruthenium complexes with organic azides Journal of The Chemical Society-dalton Transactions. pp. 3177- 3184 ,(1997) , 10.1039/A703028B
Samia Kahlal, Jean-Yves Saillard, Jean-Rene´ Hamon, Carolina Manzur, David Carrillo, Bonding analysis of transition metal NNR end-on complexes and comparison with isoelectronic NNR2 species New Journal of Chemistry. ,vol. 25, pp. 231- 242 ,(2001) , 10.1039/B005916L
Sergio Cenini, Emma Gallo, Alessandro Caselli, Fabio Ragaini, Simone Fantauzzi, Cristiana Piangiolino, Coordination chemistry of organic azides and amination reactions catalyzed by transition metal complexes Coordination Chemistry Reviews. ,vol. 250, pp. 1234- 1253 ,(2006) , 10.1016/J.CCR.2005.10.002
Andreas A. Danopoulos, Geoffrey Wilkinson, Tracy K. N. Sweet, Michael B. Hursthouse, Reactions of imido complexes of iridium, rhodium and ruthenium Journal of The Chemical Society-dalton Transactions. pp. 3771- 3778 ,(1996) , 10.1039/DT9960003771
Daniel J. Mindiola, Hydrazidokomplexe früher Übergangsmetalle: maskierte Metallanitrene durch Spaltung von N‐N‐Bindungen Angewandte Chemie. ,vol. 120, pp. 1580- 1583 ,(2008) , 10.1002/ANGE.200704987
Yasuhiro Ohki, Michael D. Fryzuk, Aktivierung von Distickstoff durch Komplexe von Metallen der Gruppe 4 Angewandte Chemie. ,vol. 119, pp. 3242- 3245 ,(2007) , 10.1002/ANGE.200605245