作者: William R. Shields , Thomas J. Murphy , Edward J. Catanzaro , Ernest L. Garner
关键词: Isotope 、 Analytical chemistry 、 Mass number 、 Isotopes of copper 、 Isotope separation 、 Natural abundance 、 Rhenium 、 Chemistry 、 Atomic mass 、 Mass spectrometry
摘要: An absolute value has been obtained for the isotopic abundance ratio of a reference sample rhenium, using surface emission mass spectrometry. Samples known composition, prepared from nearly isotopically pure separated rhenium isotopes, were used to calibrate spectrometers. The resulting 185Ke/187Re is 0.59738±0.00039, which yields atom percents 185Re = 37.398±0.016 and 187Re 62.602±0.016. atomic weight calculated this composition 186.20679±0.00031. indicated uncertainties are overall limits error based on 95 percent confidence mean allowances effects sources possible systematic error.