Origin of surface electron accumulation and fermi level pinning in low energy ion induced InN/GaN heterostructure

作者: Monu Mishra , T.C. Shibin Krishna , Mukesh Kumar , Govind Gupta

DOI: 10.1016/J.MATCHEMPHYS.2015.06.037

关键词: Electronic structureHeterojunctionIonFermi levelX-ray photoelectron spectroscopyBand offsetSubstrate (electronics)Band bendingCondensed matter physicsMaterials science

摘要: Abstract InN/GaN heterostructure was fabricated via reactive low energetic Nitrogen ion (LENI at 300 eV) bombardment lower substrate temperature (350 °C). X-Ray Photoemission spectroscopic (XPS) and Atomic Force Microscopic (AFM) measurements were performed to analyse the electronic structure, surface chemistry, band alignment, morphology of grown heterostructure. XPS analysis revealed evolution InN structure with nitridation time, electron accumulation, fermi level pinning offset hetero structure. The valence conduction offsets (VBO & CBO) calculated be 0.49 ± 0.19 eV 2.21 ± 0.1 eV divulged formation a type-I heterojunction. A Fermi Level (FL) 1.5 ± 0.1 eV above minima perceived indicated towards strong downward bending. VB spectra suggested that accumulation occurred due presence metallic In-adlayer on which resulted in FL corresponding Microscopy smooth granular It also observed growth parameters (e.g. temperature) strongly influence aforementioned interfacial properties.

参考文章(44)
Chin-An Chang, Chuan-Feng Shih, Nai-Chuan Chen, T. Y. Lin, Kuo-Shiun Liu, In-rich In1−xGaxN films by metalorganic vapor phase epitaxy Applied Physics Letters. ,vol. 85, pp. 6131- 6133 ,(2004) , 10.1063/1.1842375
Shih-Kai Lin, Kun-Ta Wu, Chao-Ping Huang, C.-T. Liang, Y. H. Chang, Y. F. Chen, P. H. Chang, N. C. Chen, C. A. Chang, H. C. Peng, C. F. Shih, K. S. Liu, T. Y. Lin, Electron transport in In-rich InxGa1−xN films Journal of Applied Physics. ,vol. 97, pp. 046101- ,(2005) , 10.1063/1.1847694
Ching-Lien Hsiao, Li-Wei Tu, Min Chen, Zhi-Wei Jiang, Ni-Wan Fan, Yen-Jie Tu, Kwang-Ru Wang, Polycrystalline to Single-Crystalline InN Grown on Si(111) Substrates by Plasma-Assisted Molecular-Beam Epitaxy Japanese Journal of Applied Physics. ,vol. 44, pp. L1076- L1079 ,(2005) , 10.1143/JJAP.44.L1076
I. Mahboob, T. D. Veal, C. F. McConville, H. Lu, W. J. Schaff, Intrinsic electron accumulation at clean InN surfaces. Physical Review Letters. ,vol. 92, pp. 036804- ,(2004) , 10.1103/PHYSREVLETT.92.036804
T. Kawabata, F. Okuyama, M. Tanemura, Fundamental and practical aspects of reactive N+2‐ion sputtering in Auger in‐depth analysis Journal of Applied Physics. ,vol. 69, pp. 3723- 3728 ,(1991) , 10.1063/1.348465
N. Karar, R. Opila, T. Beebe, Wet Etching and Surface Analysis of Chemically Treated InGaN Films Journal of The Electrochemical Society. ,vol. 158, ,(2011) , 10.1149/1.3574036
Chung-Lin Wu, Hong-Mao Lee, Cheng-Tai Kuo, Chia-Hao Chen, Shangjr Gwo, Absence of Fermi-Level Pinning at Cleaved Nonpolar InN Surfaces Physical Review Letters. ,vol. 101, pp. 106803- ,(2008) , 10.1103/PHYSREVLETT.101.106803
Hai Lu, William J. Schaff, Lester F. Eastman, C. E. Stutz, Surface charge accumulation of InN films grown by molecular-beam epitaxy Applied Physics Letters. ,vol. 82, pp. 1736- 1738 ,(2003) , 10.1063/1.1562340
K.S.A. Butcher, T.L. Tansley, InN, latest development and a review of the band-gap controversy Superlattices and Microstructures. ,vol. 38, pp. 1- 37 ,(2005) , 10.1016/J.SPMI.2005.03.004
Anuj Krishna, N. Vijayan, Shashikant Gupta, Kanika Thukral, V. Jayaramakrishnan, Budhendra Singh, J. Philip, Subhasis Das, K. K. Maurya, G. Bhagavannarayana, Key aspects of L-threoninium picrate single crystal: an excellent organic nonlinear optical material with a high laser-induced damage threshold RSC Advances. ,vol. 4, pp. 56188- 56199 ,(2014) , 10.1039/C4RA09410G