Tailoring the surface-oxygen defects of a tin dioxide support towards an enhanced electrocatalytic performance of platinum nanoparticles.
作者： Maidhily Manikandan , Toyokazu Tanabe , Gubbala V. Ramesh , Rajesh Kodiyath , Shigenori Ueda
DOI: 10.1039/C5CP04714E
关键词: Oxygen 、 Surface oxygen 、 Platinum nanoparticles 、 Tin dioxide 、 Band gap 、 Nanotechnology 、 Materials science
摘要: Tin-dioxide nanofacets (SnO2 NFs) are crystal-engineered so that oxygen defects on the maximal {113} surface long-range ordered to give rise a non-occupied defect band (DB) in bandgap. SnO2 NFs-supported platinum-nanoparticles exhibit an enhanced ethanol-electrooxidation activity due promoted charge-transport via DB at metal–semiconductor interface.
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