Tetrathiomolybdate@ZIFs nanocrystal clusters: A novel modular and controllable catalyst for photocatalytic application

摘要: Abstract Constructing MOFs-composite catalyst with satisfactory catalytic efficiency as well low cost still presents a major challenge. In this work, low-cost modular photocatalyst controllable activity is facilely fabricated by embedding ZIF-8 nanocrystal clusters ammonium tetrathiomolybdate (ATTM) (donated ZIF-MS). The embedded ATTM molecules can not only serve photocatalytic sites but also alter the nucleation and morphology of resulted ZIF-MS, showing for application. Under optimized proportion precursors, 576.52 nm ZIF-MS cluster composed 24.70 nm grain, high size selectivity degradation environmental pollutants, was obtained. combination size-selectivity structure-tunable ZIFs noble-free inorganic agent makes these ideal candidates applications.