Adsorption Inhibitors of Acid Iron Corrosion

作者: Helmut Kaesche

DOI: 10.1007/978-3-642-96038-3_7

关键词: PassivationInorganic chemistryOxidizing agentAdsorptionPicklingChemistryCorrosionCorrosion inhibitorReagentAnaerobic corrosion

摘要: By definition, corrosion inhibitors are soluble substances which, added to the aggressive solution, reduce rate without participating in overall reaction. As they not reactants reaction negative catalysts. In this chapter we shall deal with such as sodium carbonate, or other increasing pH of solution and favoring spontaneous passivation, hydrazine a reagent reducing dissolved oxygen thus removing species many neutral-solution processes. Also, disregard components protective paint systems, classical read lead oxide, Pb3O4, an intensely oxidizing again aiming at passivating iron steel surfaces. Instead, object will presently be mechanism protection by acid acting through adsorption on metal surface from containing inhibitive substance millimolar even smaller concentration only. The typical industrial application is hot-rolled against heavy loss during pickling. Another important underground gas oil well piping accompanying embrittlement attack hydrogen sulfide solutions.

参考文章(13)
Frederick E. Petry, Principles and Applications Kluwer Academic Publishers. ,(1997)
Ya. M. Kolotyrkin, Effect of specific adsorption of anions on hydrogen overvoltage Transactions of the Faraday Society. ,vol. 55, pp. 455- 462 ,(1959) , 10.1039/TF9595500455
Helmut Kaesche, Norman Hackerman, Corrosion Inhibition by Organic Amines Journal of The Electrochemical Society. ,vol. 105, pp. 191- 198 ,(1957) , 10.1149/1.2428796
N. HACKERMAN, D. D. JUSTICE, E. McCAFFERTY, Homopiperazine as a Corrosion Inhibitor Corrosion. ,vol. 31, pp. 240- 242 ,(1975) , 10.5006/0010-9312-31.7.240
Manfred H. Akstinat, Organische Korrosionsinhibitoren ‐ Wirkungsmechanismen und Charakteristik ‐ Materials and Corrosion-werkstoffe Und Korrosion. ,vol. 21, pp. 273- 281 ,(1970) , 10.1002/MACO.19700210406
T. P. Hoar, R. D. Holliday, The inhibition by quinolines and thioureas of the acid dissolution of mild steel Journal of Chemical Technology & Biotechnology. ,vol. 3, pp. 502- 513 ,(2007) , 10.1002/JCTB.5010031105
K. E. Heusler, G. H. Cartledge, The Influence of Iodide Ions and Carbon Monoxide on the Anodic Dissolution of Active Iron Journal of The Electrochemical Society. ,vol. 108, pp. 732- 740 ,(1961) , 10.1149/1.2428207
P. Delahay, Ashok K. Vijh, Advances in Electrochemistry and Electrochemical Engineering Journal of The Electrochemical Society. ,vol. 117, ,(1964) , 10.1149/1.2407311
A. C. Makrides, Norman Hackerman, Effect of Thiourea Compounds on Dissolution Rate of Iron and Mild Steel - Adsorption and Inhibition, Steady State and Potential Industrial & Engineering Chemistry. ,vol. 47, pp. 1773- 1781 ,(1955) , 10.1021/IE50549A026