Recombination and Disproportionation Reactions of Iodine Atoms and Ethyl Radicals
作者： J. A. Guercione , M. H. J. Wijnen
DOI: 10.1063/1.1733446
关键词: Iodine 、 Ketone 、 Photodissociation 、 Photochemistry 、 Radical 、 Chemistry 、 Disproportionation 、 Methyl iodide 、 Radical disproportionation 、 Recombination 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: In order to obtain information regarding disproportionation and recombination reactions of ethyl radicals iodine atoms we have investigated the photolysis various mixtures diethyl ketone methyl iodide.Ethyl radicals, produced by ketone, react with atoms, iodide, according (13) (14) C2H5+I→C2H4+HI, C2H5+I→C2H5I. The results indicate k13/k14=0.33±0.03. influence added gas effect temperature are discussed.
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