A novel chromatism switcher with double receptors selectively for Ag+ in neutral aqueous solution: 4,5-diaminoalkeneamino-N-alkyl-l,8-naphthalimides

作者: Lihua Jia , Yu Zhang , Xiangfeng Guo , Xuhong Qian

DOI: 10.1016/J.TETLET.2004.03.105

关键词: Inorganic chemistryPhotochemistryNaphthalimidesAlkylFluorescenceQuenchingAqueous solutionChemistryAbsorption (chemistry)Metal ions in aqueous solutionReceptor

摘要: Two novel fluorosensors of 4,5-disubstituted-N-alkyl-l,8-naphthalimide derivatives (H1, H2, H3) with double ethylenediamino receptors, propylenediamino or one methylpiperazine receptor were synthesized, respectively. Their fluorescence and absorption in the presence absence nine metal ions studied. In Ag+, H1's moved to long wavelength color change from yellow-green red, its quenching red shift also remarkable. Similarly, was strongly quenched Cu2+. addition, H1 H2 show high pH sensitively. There 139-folds enhancement for H1, 22-folds 4-folds H3 when changed 8 3,

参考文章(33)
A. V. Kukhto, É. É Kolesnik, M. I. Tobi, I. K. Grabchev, Electroluminescence of Belophores in a Wide Spectral Region Journal of Applied Spectroscopy. ,vol. 67, pp. 939- 942 ,(2000) , 10.1023/A:1004196607550
Massimo Boiocchi, Luigi Fabbrizzi, Maurizio Licchelli, Donatella Sacchi, Miguel Vázquez, Cristina Zampa, A two-channel molecular dosimeter for the optical detection of copper(II) Chemical Communications. pp. 1812- 1813 ,(2003) , 10.1039/B305456J
Ivo Grabchev, Ivanka Moneva, Vladimir Bojinov, Sylvie Guittonneau, Synthesis and properties of fluorescent 1,8-naphthalimide dyes for application in liquid crystal displays Journal of Materials Chemistry. ,vol. 10, pp. 1291- 1296 ,(2000) , 10.1039/A909153J
Zhi-Fu Tao, Xuhong Qian, Jun Tang, None, Synthesis of furonaphthalimides as novel DNA intercalators Dyes and Pigments. ,vol. 30, pp. 247- 252 ,(1996) , 10.1016/0143-7208(95)00082-8
Gérard Klein, Daniel Kaufmann, Stefan Schürch, Jean-Louis Reymond, A fluorescent metal sensor based on macrocyclic chelation Chemical Communications. pp. 561- 562 ,(2001) , 10.1039/B100535I
Knut Rurack, Matthias Kollmannsberger, Ute Resch-Genger, Jörg Daub, A Selective and Sensitive Fluoroionophore for HgII, AgI, and CuII with Virtually Decoupled Fluorophore and Receptor Units Journal of the American Chemical Society. ,vol. 122, pp. 968- 969 ,(2000) , 10.1021/JA992630A
Huarui He, Mark A. Mortellaro, Marc J. P. Leiner, Robert J. Fraatz, James K. Tusa, A Fluorescent Sensor with High Selectivity and Sensitivity for Potassium in Water Journal of the American Chemical Society. ,vol. 125, pp. 1468- 1469 ,(2003) , 10.1021/JA0284761
Jongmin Kang, Miwhoa Choi, Ji Young Kwon, Eun Yeol Lee, Juyoung Yoon, New fluorescent chemosensors for silver ion. Journal of Organic Chemistry. ,vol. 67, pp. 4384- 4386 ,(2002) , 10.1021/JO020123X