Optical and structural properties of drop-cast PVA/PEG polyblends

作者: Jitender Paul Sharma , Praveen Kumar , Kiran Sharma , Manoj Kumar , Amit Arora

DOI: 10.1016/J.MATPR.2020.03.801

关键词: Absorption edgeMaterials scienceCrystallizationPEG ratioScanning electron microscopePolyethylene glycolChemical engineeringPolyvinyl alcoholPolymerFourier transform infrared spectroscopy

摘要: Abstract In the present study, drop cast films of polyvinyl alcohol (PVA), polyethylene glycol (PEG) and optimized PVA:PEG (50:50) polyblend were studied. The pure polymer polyblends samples characterised by using Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR) Optical Absorption Spectroscopic Techniques. Changes in morphology has been observed SEM photographs. FTIR results have to form H-bond between PVA PEG which confirms plasticizing effect on PVA. absorption maxima is at 325 nm 300 nm for samples, while it found shift 320 nm polyblends. peak related edge may attribute change polymeric chain mobility as well crystallization behaviour during blending process. value indirect optical gap be 1.75 eV, very less compared components. An increase B−1 indicating an enhancement disorder with formation These are important realizing their applications

参考文章(22)
M. Hema, S. Selvasekarapandian, D. Arunkumar, A. Sakunthala, H. Nithya, FTIR, XRD and ac impedance spectroscopic study on PVA based polymer electrolyte doped with NH4X (X = Cl, Br, I) Journal of Non-crystalline Solids. ,vol. 355, pp. 84- 90 ,(2009) , 10.1016/J.JNONCRYSOL.2008.10.009
M. I. Abd-Elrahman, Synthesis of Polyvinyl Alcohol–Zinc Oxide Composite by Mechanical Milling: Thermal and Infrared Studies Nanoscale and Microscale Thermophysical Engineering. ,vol. 17, pp. 194- 203 ,(2013) , 10.1080/15567265.2013.776152
P. A. Sreekumar, Mamdouh A. Al-Harthi, S. K. De, Effect of glycerol on thermal and mechanical properties of polyvinyl alcohol/starch blends Journal of Applied Polymer Science. ,vol. 123, pp. 135- 142 ,(2012) , 10.1002/APP.34465
Z. I. Ali, W. H. Eisa, Characterization of Electron Beam Irradiated Poly Vinyl Alcohol / Poly Ethylene Glycol Blends Journal of Scientific Research. ,vol. 6, pp. 29- 42 ,(2013) , 10.3329/JSR.V6I1.13071
S. A. Nouh, A. G. Nagla, M. H. Othman, S. A. Eman, Z. I. Lotfi, Thermal, structural, and optical properties of γ-irradiated poly(vinyl alcohol)/poly(ethylene glycol) thin film Journal of Applied Polymer Science. ,vol. 124, pp. 654- 660 ,(2012) , 10.1002/APP.35010
Xiaoqian Xu, Kesong Miao, Yun Chen, Li-Juan Fan, Preparation of Fluorescent Conjugated Polymer Fibrous Membranes for Rapid Recognition of Aromatic Solvents ACS Applied Materials & Interfaces. ,vol. 7, pp. 7759- 7766 ,(2015) , 10.1021/ACSAMI.5B00991
Jobin Jose, Mamdouh A Al‐Harthi, Mariam Al‐Ali AlMa'adeed, Jolly Bhadra Dakua, Sadhan K De, None, Effect of graphene loading on thermomechanical properties of poly(vinyl alcohol)/starch blend Journal of Applied Polymer Science. ,vol. 132, ,(2015) , 10.1002/APP.41827
C.YOHANNAN PANICKER, HEMA TRESA VARGHESE, Y. SHEENA MARY, FTIR, FT-Raman and DFT Calculations of 5-nitro-1,3-Benzodioxole Oriental journal of chemistry. ,vol. 28, pp. 1037- 1041 ,(2012) , 10.13005/OJC/280256