Anionic copolymerization of diglycidyl ether of bisphenol A with Meldrum's acid derivatives initiated by 4‐(N,N‐dimethylamino) pyridine
作者： Lidia González , Xavier Ramis , Josep Maria Salla , Ana Mantecón , Angels Serra
DOI: 10.1002/APP.29211
关键词: Fourier transform infrared spectroscopy 、 Diglycidyl ether 、 Chemistry 、 Bisphenol A 、 Polymer chemistry 、 Curing (chemistry) 、 Meldrum's acid 、 Epoxide 、 Ring-opening polymerization 、 Pyridine
摘要: The anionic copolymerization of diglycidyl ether bisphenol A with 2,2,5,5-tetramethyl-4,6-dioxo-1,3-dioxane or 6,6-dimethyl-(4,8-dioxaspiro[2.5]octane-5,7-dione) 4-(N,N-dimethylamino) pyridine as an initiator to form thermosets was studied differential scanning calorimetry, and the kinetics were evaluated isoconversional procedures. evolution during curing process epoxide, lactone, linear ester bands Fourier transform infrared spectroscopy in attenuated total reflection mode clarify reactions taking place. shrinkage curing, thermomechanical properties, thermal degradability materials obtained by different derivatives Meldrum's acid related chemical structure final network.
sci-hub.se 参考文章(34)
Theoretical Studies on the Structure and Acidity of Meldrum's Acid and Related Compounds Bulletin of The Korean Chemical Society. ,vol. 24, pp. 1141- 1149 ,(2003) , 10.5012/BKCS.2003.24.8.1141
X. Ramis,, J. M. Salla, A. Cadenato, J. M. Morancho, Simulation of isothermal cure of A powder coating Journal of Thermal Analysis and Calorimetry. ,vol. 72, pp. 707- 718 ,(2003) , 10.1023/A:1024562607857
H. E. Kissinger, Reaction Kinetics in Differential Thermal Analysis Analytical Chemistry. ,vol. 29, pp. 1702- 1706 ,(1957) , 10.1021/AC60131A045
Lidia González, Xavier Ramis, Josep Maria Salla, Angels Serra, Ana Mantecón, New thermosets obtained from DGEBA and Meldrum acid with lanthanum and ytterbium triflates as cationic initiators European Polymer Journal. ,vol. 44, pp. 1535- 1547 ,(2008) , 10.1016/J.EURPOLYMJ.2008.02.019
Jir-Shyr Chen, Christopher K. Ober, Mark D. Poliks, Characterization of thermally reworkable thermosets: materials for environmentally friendly processing and reuse Polymer. ,vol. 43, pp. 131- 139 ,(2002) , 10.1016/S0032-3861(01)00605-X
X. Fernández-Francos, J.M. Salla, A. Mantecón, A. Serra, X. Ramis, Crosslinking of mixtures of DGEBA with 1,6-dioxaspiro[4.4]nonan-2, 7-dione initiated by tertiary amines, Part II: Thermo-mechanical properties and reworkability Polymer Degradation and Stability. ,vol. 93, pp. 760- 769 ,(2008) , 10.1016/J.POLYMDEGRADSTAB.2008.01.025
Jir-Shyr Chen, Christopher K Ober, Mark D Poliks, Yuanming Zhang, Ulrich Wiesner, Claude Cohen, Controlled degradation of epoxy networks: analysis of crosslink density and glass transition temperature changes in thermally reworkable thermosets Polymer. ,vol. 45, pp. 1939- 1950 ,(2004) , 10.1016/J.POLYMER.2004.01.011
Cristina Mas, Xavier Ramis, Josep Maria Salla, Ana Mantecón, Angels Serra, Cationic copolymerization of diglycidyl ether of bisphenol A with phthalide or 3,3′‐diphtalide catalyzed by lanthanide triflates Journal of Polymer Science Part A. ,vol. 44, pp. 1711- 1721 ,(2006) , 10.1002/POLA.21285
Hamish McNab, Meldrum's acid Chemical Society Reviews. ,vol. 7, pp. 345- 358 ,(1978) , 10.1039/CS9780700345
J. Canadell, A. Mantecón, V. Cádiz, Novel silicon‐containing spiroorthoester to confer combined flame retardancy and low shrinkage properties to epoxy resins Journal of Polymer Science Part A. ,vol. 45, pp. 4211- 4224 ,(2007) , 10.1002/POLA.22164