Thermoresponsive oligo(ethylene glycol)-methacrylate- based polymers and microgels
作者： Zhibing Hu , Tong Cai , Chenglin Chi
DOI: 10.1039/B921150K
关键词: Biocompatibility 、 Methacrylate 、 Ethylene glycol 、 Self-healing hydrogels 、 Polymer chemistry 、 Polymer 、 Coating 、 Radical polymerization 、 Dispersity 、 Chemical engineering 、 Materials science
摘要: Since Lutz's and coworkers 2006 J. Am. Chem. Soc. paper on thermoresponsive properties of poly-oligo(ethylene glycol) methacrylates (POEGMA), the publications these polymers have grown rapidly. This highlight will cover some latest progresses in this active field. The selected topics include synthesizing POEGMA with various structures via controlled free radical polymerization techniques, coating flat particle surfaces to impart thermo-responsive antifouling materials, preparing biodegradable nanogels for drug release, using monodisperse microgels as building blocks form photonic hydrogels. As similarity self-assembling between poly-N-isopropylacrylamide (PNIPAM) has been established, many previous works PNIPAM could be applied polymers. studies open a new avenue stimuli responsive polymer research because advantages over including biocompatibility resistance absorption proteins.
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