Sensitized photoreaction of diacetylene multilayers

作者: C. Bubeck , K. Weiss , B. Tieke

DOI: 10.1016/0040-6090(83)90365-6

关键词: PhotopolymerDiacetylenePhotochemistryCyanineVisible spectrumPolymer yieldAnthraquinoneChemistry

摘要: The photopolymerization of diacetylene multilayers can be sensitized for visible light by surface-active acridinium and anthraquinone dyes embedded in the layers. same polymer yield is obtained as direct UV excitation units or using cyanine sensitizers. mechanism sensitization discussed.

参考文章(15)
J.L. Hardwick, D.A. Ramsay, The near ultraviolet and band system of diacetylene Chemical Physics Letters. ,vol. 48, pp. 399- 401 ,(1977) , 10.1016/0009-2614(77)85055-0
C. Bubeck, B. Tieke, G. Wegner, Cyanine Dyes as Sensitizers of the Photopolymerization of Diacetylenes in Multilayers Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 86, pp. 499- 504 ,(1982) , 10.1002/BBPC.19820860605
C. Bubeck, H. Sixl, H.C. Wolf, ESR of the low temperature photoproducts in a diacetylene single crystal principles and practice of constraint programming. ,vol. 32, pp. 231- 237 ,(1978) , 10.1016/0301-0104(78)87055-4
Adrien Albert, Reginald Goldacre, Eric Heymann, 171. Aminoacridines: some partition and surface phenomena Journal of The Chemical Society (resumed). pp. 651- 654 ,(1943) , 10.1039/JR9430000651
M. Bertault, J.L. Fave, M. Schott, The lowest triplet state of a diacetylene Chemical Physics Letters. ,vol. 62, pp. 161- 165 ,(1979) , 10.1016/0009-2614(79)80434-0
Tetsuko Takabe, Masashi Tanaka, Jiro Tanaka, The Electronic Spectra of Diphenylacetylene and 1,3-Butadiyne Bulletin of the Chemical Society of Japan. ,vol. 47, pp. 1912- 1916 ,(1974) , 10.1246/BCSJ.47.1912
M. Ashraf El‐Bayoumi, Omar S. Khalil, n and π Ionization Potentials of Nitrogen Heterocyclic Molecules from Charge‐Transfer Absorption of Their Complexes The Journal of Chemical Physics. ,vol. 47, pp. 4863- 4864 ,(1967) , 10.1063/1.1701722
J. P. Fouassier, B. Tieke, G. Wegner, The Photochemistry of the Polymerization of Diacetylenes in Multilayers Israel Journal of Chemistry. ,vol. 18, pp. 227- 232 ,(1979) , 10.1002/IJCH.197900033
Kiyoshige Fukuda, Hiroo Nakahara, Teiji Kato, Monolayers and multilayers of anthraquinone derivatives containing long alkyl chains Journal of Colloid and Interface Science. ,vol. 54, pp. 430- 438 ,(1976) , 10.1016/0021-9797(76)90323-4