Synthesis and properties of electrically conducting polymers from aromatic amines

作者: T Hagiwara , T Demura , K Iwata

DOI: 10.1016/0379-6779(87)90898-8

关键词: PolymerOrganic chemistryChemistryPolymerizationAmmonium persulfateConductive polymerPolyanilineAnilineGroup (periodic table)MoleculePolymer chemistry

摘要: Abstract Various aromatic amines were polymerized by oxidation using ammonium persulfate. Among these, a group of found to give polymers substantially identical the polymer from aniline. The molecular structure polyaniline was investigated N,N′-diphenyl- p -phenylenediamine and -quinonediimine as model compounds.

参考文章(4)
Anatole Volkov, Gérard Tourillon, Pierre-Camille Lacaze, Jacques-Emile Dubois, Electrochemical polymerization of aromatic amines Journal of Electroanalytical Chemistry. ,vol. 115, pp. 279- 291 ,(1980) , 10.1016/S0022-0728(80)80332-9
Takeo Ohsaka, Yukio Ohnuki, Noboru Oyama, Gen Katagiri, Koichi Kamisako, IR absorption spectroscopic identification of electroactive and electroinactive polyaniline films prepared by the electrochemical polymerization of aniline Journal of Electroanalytical Chemistry. ,vol. 161, pp. 399- 405 ,(1984) , 10.1016/S0022-0728(84)80198-9
Jin-Chih Chiang, Alan G MacDiarmid, ‘Polyaniline’: Protonic acid doping of the emeraldine form to the metallic regime Synthetic Metals. ,vol. 13, pp. 193- 205 ,(1986) , 10.1016/0379-6779(86)90070-6
Henry. Linschitz, Michael. Ottolenghi, Rene. Bensasson, One-electron oxidation of triplet diphenyl-p-phenylenediamine by the diimine Journal of the American Chemical Society. ,vol. 89, pp. 4592- 4599 ,(1967) , 10.1021/JA00994A005