Determination of five major anthraquinoids in Chinese herbal preparations by micellar electrokinetic capillary electrophoresis
作者： Shuenn-Jyi Sheu , Hong-Ren Chen
DOI: 10.1016/0003-2670(95)00034-W
关键词: Electrophoresis 、 Acetonitrile 、 Sodium dodecyl sulfate 、 Chemistry 、 Anthrone 、 Emodin 、 Chromatography 、 Capillary electrophoresis 、 Buffer solution 、 Sodium
摘要: Abstract A micellar electrokinetic capillary electrophoretic (MEKC) method was developed for the simultaneous assay of three anthraquinones (rhein, emodin and aloe-emodin) two anthrones (sennoside sennoside B) in Chinese herbal preparations. The carrier composed a buffer solution (10 mM sodium dodecyl sulfate, 12.5 dihydrogenphosphate 15 borate) acetonitrile (3:1) found to be most suitable electrolyte this separation, whereby contents these anthraquinoids rhubarb-containing preparations could easily determined within 30 min. effects surfactant concentration organic modifier (acetonitrile) on migration separation solutes were also studied.
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sci-hub.se 参考文章(11)
Eiichi Obataya, Yoshiki KASHIWADA, Gen-ichiro NONAKA, Itsuo NISHIOKA, Studies on Rhubarb (Rhei Rhizoma). XV. : Simultaneous Determination of Phenolic Constituents by High-Performance Liquid Chromatography Chemical & Pharmaceutical Bulletin. ,vol. 37, pp. 999- 1004 ,(1989) , 10.1248/CPB.37.999
Ying-Mei Liu, Shuenn-Jyi Sheu, Determination of the six major flavonoids in Scutellariae Radix by micellar electrokinetic capillary electrophoresis Analytica Chimica Acta. ,vol. 288, pp. 221- 226 ,(1994) , 10.1016/0003-2670(94)80134-7
Szabolcs Nyiredy, Karin Dallenbach-Toelke, Georg C. Zogg, Otto Sticher, Strategies of mobile phase transfer from thin-layer to medium-pressure liquid chromatography with silica is the stationary phase Journal of Chromatography A. ,vol. 499, pp. 453- 462 ,(1990) , 10.1016/S0021-9673(00)96991-7
Yukio Ohshima, Yohei Ohno, Kiichiro Kajiyama, Kunio Takahashi, High-performance liquid chromatographic separation of rhubarb constituents Journal of Chromatography A. ,vol. 360, pp. 303- 306 ,(1986) , 10.1016/S0021-9673(00)91680-7
Quan-xun Dang, Zeng-pei Sun, Da-Kui Ling, Separation of sulphonamides and determination of the active ingredients in tablets by micellar electrokinetic capillary chromatography Journal of Chromatography A. ,vol. 603, pp. 259- 266 ,(1992) , 10.1016/0021-9673(92)85369-5
Kazuhiko Sagara, Toshiyuki Oshima, Tsuguchika Yoshida, Rapid and simple determination of sennoside A and B in rhei rhizoma by ion-pair high-performance liquid chromatography. Journal of Chromatography A. ,vol. 403, pp. 253- 261 ,(1987) , 10.1016/S0021-9673(00)96359-3
Eris Singer, H. J. Möckel, RPLC retention of 1,ω-di(alkoxy)-polysulphides Chromatographia. ,vol. 27, pp. 27- 30 ,(1989) , 10.1007/BF02290400
James R. Poulsen, John W. Birks, Photoreduction fluorescence detection of quinones in high-performance liquid chromatography Analytical Chemistry. ,vol. 61, pp. 2267- 2276 ,(1989) , 10.1021/AC00195A012
Richard Evans Schultes, The chemical constituents of oriental herbs: Hong-Zen Hsu, Yuh-Pan Chen and Mina Hong, Oriental Healing Arts Institute of the United States, 8820 South Sepulveda Blvd., Suite 218, Los Angeles, CA, 1982, vii + 1546 pp. (US$75.00) Journal of Ethnopharmacology. ,vol. 10, pp. 197- ,(1984) , 10.1016/0378-8741(84)90027-8
Xueyi Ma, Yaozu Chen, Ruihua Hui, Analysis of anthraquinones inRheum franzenbachii Münt (rhubarb) by thin-layer chromatography Chromatographia. ,vol. 27, pp. 465- 466 ,(1989) , 10.1007/BF02319565