Porous Multishelled Ni2P Hollow Microspheres as an Active Electrocatalyst for Hydrogen and Oxygen Evolution
作者： Hongming Sun , Xiaobin Xu , Zhenhua Yan , Xiang Chen , Fangyi Cheng
DOI: 10.1021/ACS.CHEMMATER.7B03627
关键词: Nanoparticle 、 Electrocatalyst 、 Anode 、 Electrolyte 、 Oxygen evolution 、 Hydrogen 、 Catalysis 、 Inorganic chemistry 、 Polarization (electrochemistry) 、 Materials science
摘要: Tailoring the morphology and microstructure of electrocatalysts is important in improving catalytic performance. Herein, porous multishelled Ni2P hollow microspheres assembled by nanoparticles were prepared through a simple and economical self-templating approach followed by phosphorization. Compared with nanoparticles and hierarchical solid-interior microspheres, the synthesized multishelled, hollow microstructures of Ni2P exhibit significantly higher electrocatalytic activity for the hydrogen evolution reaction in a 1 M KOH …
acs.org
sci-hub.se 参考文章(64)
Jing Du, Chengcheng Chen, Fangyi Cheng, Jun Chen, Rapid Synthesis and Efficient Electrocatalytic Oxygen Reduction/Evolution Reaction of CoMn2O4 Nanodots Supported on Graphene Inorganic Chemistry. ,vol. 54, pp. 5467- 5474 ,(2015) , 10.1021/ACS.INORGCHEM.5B00518
Xia Long, Guixia Li, Zilong Wang, HouYu Zhu, Teng Zhang, Shuang Xiao, Wenyue Guo, Shihe Yang, Metallic Iron–Nickel Sulfide Ultrathin Nanosheets As a Highly Active Electrocatalyst for Hydrogen Evolution Reaction in Acidic Media Journal of the American Chemical Society. ,vol. 137, pp. 11900- 11903 ,(2015) , 10.1021/JACS.5B07728
Jian Qi, Xiaoyong Lai, Jiangyan Wang, Hongjie Tang, Hao Ren, Yu Yang, Quan Jin, Lijuan Zhang, Ranbo Yu, Guanghui Ma, Zhiguo Su, Huijun Zhao, Dan Wang, Multi-shelled hollow micro-/nanostructures Chemical Society Reviews. ,vol. 44, pp. 6749- 6773 ,(2015) , 10.1039/C5CS00344J
Ali Han, Huanlin Chen, Zijun Sun, Jun Xu, Pingwu Du, High catalytic activity for water oxidation based on nanostructured nickel phosphide precursors Chemical Communications. ,vol. 51, pp. 11626- 11629 ,(2015) , 10.1039/C5CC02626A
Hai-Wei Liang, Sebastian Brüller, Renhao Dong, Jian Zhang, Xinliang Feng, Klaus Müllen, Molecular metal–Nx centres in porous carbon for electrocatalytic hydrogen evolution Nature Communications. ,vol. 6, pp. 7992- 7992 ,(2015) , 10.1038/NCOMMS8992
Ming Gong, Wu Zhou, Mon-Che Tsai, Jigang Zhou, Mingyun Guan, Meng-Chang Lin, Bo Zhang, Yongfeng Hu, Di-Yan Wang, Jiang Yang, Stephen J. Pennycook, Bing-Joe Hwang, Hongjie Dai, Nanoscale nickel oxide/nickel heterostructures for active hydrogen evolution electrocatalysis Nature Communications. ,vol. 5, pp. 4695- ,(2014) , 10.1038/NCOMMS5695
Zhen-guo Wu, Yan-jun Zhong, Jun-tao Li, Xiao-dong Guo, Ling Huang, Ben-he Zhong, Shi-gang Sun, L-Histidine-assisted template-free hydrothermal synthesis of α-Fe2O3 porous multi-shelled hollow spheres with enhanced lithium storage properties Journal of Materials Chemistry. ,vol. 2, pp. 12361- 12367 ,(2014) , 10.1039/C4TA01253D
Peter E. R. Blanchard, Andrew P. Grosvenor, Ronald G. Cavell, Arthur Mar, X-ray Photoelectron and Absorption Spectroscopy of Metal-Rich Phosphides M2P and M3P (M = Cr−Ni) Chemistry of Materials. ,vol. 20, pp. 7081- 7088 ,(2008) , 10.1021/CM802123A
Ali Han, Song Jin, Huanlin Chen, Hengxing Ji, Zijun Sun, Pingwu Du, A robust hydrogen evolution catalyst based on crystalline nickel phosphide nanoflakes on three-dimensional graphene/nickel foam: high performance for electrocatalytic hydrogen production from pH 0–14 Journal of Materials Chemistry. ,vol. 3, pp. 1941- 1946 ,(2015) , 10.1039/C4TA06071G
Laifa Shen, Le Yu, Hao Bin Wu, Xin-Yao Yu, Xiaogang Zhang, Xiong Wen Lou, Formation of nickel cobalt sulfide ball-in-ball hollow spheres with enhanced electrochemical pseudocapacitive properties Nature Communications. ,vol. 6, pp. 6694- 6694 ,(2015) , 10.1038/NCOMMS7694