Controllable preparation and catalytic performance of Pd/anodic alumina oxide@Al catalyst for hydrogenation of ethylanthraquinone
作者： Runrun Hong , Junting Feng , Yufei He , Dianqing Li
DOI: 10.1016/J.CES.2015.04.003
关键词: Anthraquinone 、 Oxide 、 Catalysis 、 Diffusion 、 Inorganic chemistry 、 Hydrogen peroxide 、 Materials science 、 Anthraquinone process 、 Anodizing 、 Selectivity
摘要: Abstract Anodic alumina oxide (AAO) supports with different pore sizes and depths were controllable prepared by a two-step low-potential anodizing process. The AAO θ-ring shape utilized to prepare supported Pd catalysts impregnation method for the first time. catalytic performance of Pd/AAO@Al investigated in hydrogenation 2-ethylanthraquinone (eAQ) 2-ethylanthrahydroquinone, key step anthraquinone process manufacture hydrogen peroxide. Compared on spherical Al 2 O 3 catalyst, showed much higher activity preferable selectivity due highly ordered array cylindrical shaped pores, short diffusion distance confinement effect supports. Furthermore, size depth towards eAQ has also been studied. nanoparticles support 24.5 nm 18 μm exhibited best eAQ.
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sci-hub.se 参考文章(27)
A. Drelinkiewicz, R. Laitinen, R. Kangas, J. Pursiainen, 2-Ethylanthraquinone hydrogenation on Pd/Al2O3 The effect of water and NaOH on the degradation process Applied Catalysis A-general. ,vol. 284, pp. 59- 67 ,(2005) , 10.1016/J.APCATA.2005.01.018
Alicja Drelinkiewicz, Anna Waksmundzka-Góra, J.W. Sobczak, Jaroslav Stejskal, Hydrogenation of 2-ethyl-9,10-anthraquinone on Pd-polyaniline(SiO2) composite catalyst: The effect of humidity Applied Catalysis A-general. ,vol. 333, pp. 219- 228 ,(2007) , 10.1016/J.APCATA.2007.09.011
Hui Shang, Hongjun Zhou, Zehua Zhu, Wenhui Zhang, Study on the new hydrogenation catalyst and processes for hydrogen peroxide through anthraquinone route Journal of Industrial and Engineering Chemistry. ,vol. 18, pp. 1851- 1857 ,(2012) , 10.1016/J.JIEC.2012.04.017
J. K. Edwards, B. Solsona, E. N. N, A. F. Carley, A. A. Herzing, C. J. Kiely, G. J. Hutchings, Switching Off Hydrogen Peroxide Hydrogenation in the Direct Synthesis Process Science. ,vol. 323, pp. 1037- 1041 ,(2009) , 10.1126/SCIENCE.1168980
Jianwei Zheng, Haiqiang Lin, Xinlei Zheng, Xinping Duan, Youzhu Yuan, Highly efficient mesostructured Ag/SBA-15 catalysts for the chemoselective synthesis of methyl glycolate by dimethyl oxalate hydrogenation Catalysis Communications. ,vol. 40, pp. 129- 133 ,(2013) , 10.1016/J.CATCOM.2013.06.022
R. Kosydar, A. Drelinkiewicz, J. P. Ganhy, Degradation Reactions in Anthraquinone Process of Hydrogen Peroxide Synthesis Catalysis Letters. ,vol. 139, pp. 105- 113 ,(2010) , 10.1007/S10562-010-0413-1
E. Santacesaria, M. Di Serio, A. Russo, U. Leone, R. Velotti, Kinetic and catalytic aspects in the hydrogen peroxide production via anthraquinone Chemical Engineering Science. ,vol. 54, pp. 2799- 2806 ,(1999) , 10.1016/S0009-2509(98)00377-7
O. Jessensky, F. Müller, U. Gösele, Self-organized formation of hexagonal pore arrays in anodic alumina Applied Physics Letters. ,vol. 72, pp. 1173- 1175 ,(1998) , 10.1063/1.121004
Elio Santacesaria, Martino Di Serio, P Iengo, Examples of hydrogenation in semibatch and continuous slurry reactors Catalysis Today. ,vol. 52, pp. 363- 376 ,(1999) , 10.1016/S0920-5861(99)00088-7
Josef Petr, Ladislav Kurc, Zdeněk Bělohlav, Libor Červený, Catalytic hydrogenation of 2-ethyl-9,10-anthrahydroquinone Chemical Engineering and Processing. ,vol. 43, pp. 887- 894 ,(2004) , 10.1016/S0255-2701(03)00111-9