A Kinetic–Equilibrium Study of a Triiodide Concentration Maximum Formed by the Persulfate–Iodide Reaction
作者： Arthur E. Burgess , John C. Davidson
DOI: 10.1021/ED200055T
关键词: Inorganic chemistry 、 Iodine 、 Ultraviolet visible spectroscopy 、 Iodide 、 Iodine clock reaction 、 Triiodide 、 Analytical chemistry 、 Ion 、 Chemistry 、 Persulfate 、 Absorbance
摘要: … persulfate in excess, was started by quickly mixing equal volumes, kept at 20 ± 0.5 C, of … persulfate (100 mM) and a solution containing potassium iodide (1000 μM) and ascorbic acid (…
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P. C. Moews, R. H. Petrucci, The oxidation of iodide ion by persulfate ion Journal of Chemical Education. ,vol. 41, pp. 549- ,(1964) , 10.1021/ED041P549
Douglas H. Turner, George W. Flynn, Norman Sutin, James V. Beitz, Laser Raman temperature-jump study of the kinetics of the triiodide equilibrium. Relaxation times in the 10-8 -10-7 second range Journal of the American Chemical Society. ,vol. 94, pp. 1554- 1559 ,(1972) , 10.1021/JA00760A020
Stephen W. Wright, Tick Tock, a Vitamin C Clock Journal of Chemical Education. ,vol. 79, pp. 40- ,(2002) , 10.1021/ED079P40A
Normal V. Klassen, David. Marchington, Heather C.E. McGowan, H2O2 Determination by the I3- Method and by KMnO4 Titration Analytical Chemistry. ,vol. 66, pp. 2921- 2925 ,(1994) , 10.1021/AC00090A020
Ed Vitz, A Student Laboratory Experiment Based on the Vitamin C Clock Reaction. Journal of Chemical Education. ,vol. 84, pp. 1156- 1157 ,(2007) , 10.1021/ED084P1156
Hadas Mamane, Joel J. Ducoste, Karl G. Linden, Effect of particles on ultraviolet light penetration in natural and engineered systems. Applied Optics. ,vol. 45, pp. 1844- 1856 ,(2006) , 10.1364/AO.45.001844
Yuen-ying Carpenter, Heather A. Phillips, Michael B. Jakubinek, Clock Reaction: Outreach Attraction Journal of Chemical Education. ,vol. 87, pp. 945- 947 ,(2010) , 10.1021/ED100298E
Ronald O. Rahn, Mihaela I. Stefan, James R. Bolton, Evan Goren, Ping-Shine Shaw, Keith R. Lykke, Quantum Yield of the Iodide–Iodate Chemical Actinometer: Dependence on Wavelength and Concentration¶ Photochemistry and Photobiology. ,vol. 78, pp. 146- 152 ,(2003) , 10.1562/0031-8655(2003)078<0146:QYOTIC>2.0.CO;2