Anisotropic Growth of Silver Crystals with Ethylenediamine Tetraacetate and Formation of Planar and Stacked Wires

作者: Hiroaki Imai , Hitoshi Nakamura , Tomoyuki Fukuyo

DOI: 10.1021/CG0496585

关键词: Scanning electron microscopeSilver nitrateTransition metalElectron diffractionChemistryAqueous solutionNanowireAscorbic acidStackingCrystallography

摘要: The morphology of silver crystals grown at the liquid−liquid interface between nitrate and ascorbic acid solutions was investigated in presence various organic molecules. addition ethylenediamine tetraacetate changed from dendrites plates into single-crystalline wires with a width 100−1000 nm. were produced by elongation stacking planar exhibiting {111} faces. anisotropic growth behavior causing wire formation is tentatively ascribed to stepwise capping specific surfaces molecules having multiple carboxyl groups.

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