High pressure luminescence spectra of CaMoO4:Pr3+

作者: S Mahlik , M Grinberg , E Cavalli , M Bettinelli

DOI: 10.1088/0953-8984/24/21/215402

关键词: SpectroscopyExcited stateExcitonChemistryDopingHydrostatic pressureAtomic physicsPraseodymiumPhase transitionCondensed matter physicsLuminescence

摘要: Steady state and time resolved luminescence measurements of CaMoO4 doped with Pr3+ as a function hydrostatic pressure in the 1?175?kbar range are presented. It has been observed that increasing spectral features shift towards lower energies, decay times both 3P0 1D2 emitting levels become shorter intensity emission decreases to complete quenching at about 110?kbar, whereas increases 0?100?kbar then rapidly when exceeds 127?kbar. A variation structure manifolds indicates induced phase transition host lattice occurs 80?100?kbar range. The shortening have accounted for by means model takes into account role played praseodymium trapped exciton excited dynamics investigated material.

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