Soft Chemical Modification of Blue Potassium Molybdenum Bronze
作者： Nobukazu Kinomura , Katsuya Mizumoto , Nobuhiro Kumada
关键词: Inorganic chemistry 、 Intercalation (chemistry) 、 Catalysis 、 Amine gas treating 、 Molybdenum bronze 、 Potassium 、 Hydrogen 、 Carbon 、 Chemistry 、 Redox titration
摘要: Abstract Hydrogen insertion compounds of general formula HxK0.28MoO3·zH2O have been obtained from blue potassium molybdenum bronze (K0.28MoO3) by the spillover technique using hydrogen gas in presence a Pt catalyst. The are formed topotactically and original is regenerated standing air for at least >2 weeks. Although values ofxexceeding approximately 0.42 could not be determined redox titration, value ofxwas estimated to 1.3 immediately after about 20 h. hydrated compound undergoes intercalation reactions withn-alkylamines. basal spacing increases linearly with number carbon atoms. electric resistivity was increased order 104as result amine intercalation.
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