Enantioselective catalysis of epoxidation by metalloporphyrins: application to enantioselective synthesis
作者： Lara A. Campbell , Thomas Kodadek
DOI: 10.1016/S1381-1169(96)00164-1
关键词: Olefin fiber 、 Catalysis 、 Selectivity 、 Chemistry 、 Porphyrin 、 Enantioselective synthesis 、 Organic chemistry
摘要: A wide variety of asymmetric metalloporphyrins have been prepared in an effort to develop catalysts for the enantioselective epoxidation unfunctionalized olefins. As yet, no porphyrin-based catalyst has shown sufficient selectivity be applied general synthesis. Therefore, this review focuses specifically on developments that are leading toward synthetically useful metalloporphyrin catalyst, addressing stability and activity, ease preparation, potential improvement specific designs.
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sci-hub.se 参考文章(44)
Roger A. Sheldon, Metalloporphyrins in catalytic oxidations Marcel Dekker. ,(1994)
C. Brown, Chirality in drug design and synthesis Academic Press. ,(1990)
Iwao Ojima, Catalytic asymmetric synthesis ,(1993)
Saul Patai, The chemistry of the ether linkage Interscience Publishers. ,(1967)
Metalloporphyrins catalyzed oxidations Kluwer Academic Publishers. ,(1994) , 10.1007/978-94-017-2247-6
Tsutomu Katsuki, K. Barry Sharpless, First practical method for asymmetric epoxidation Journal of the American Chemical Society. ,vol. 102, pp. 5974- 5976 ,(1981) , 10.1021/JA00538A077
J. Collman, X Zhang, V. Lee, E. Uffelman, J. Brauman, Regioselective and enantioselective epoxidation catalyzed by metalloporphyrins Science. ,vol. 261, pp. 1404- 1411 ,(1993) , 10.1126/SCIENCE.8367724
Ronald L. Halterman, Shyi Tai Jan, Catalytic asymmetric epoxidation of unfunctionalized alkenes using the first D4-symmetric metallotetraphenylporphyrin Journal of Organic Chemistry. ,vol. 56, pp. 5253- 5254 ,(1991) , 10.1021/JO00018A008
James P. Collman, John I. Brauman, Jeffrey P. Fitzgerald, Philip D. Hampton, Yoshinori. Naruta, John W. Sparapany, James A. Ibers, Synthesis, characterization, and x-ray structure of the ruthenium picnic-basket porphyrins Journal of the American Chemical Society. ,vol. 110, pp. 3477- 3486 ,(1988) , 10.1021/JA00219A023
Yoshinori Naruta, Nobuo Ishihara, Fumito Tani, Kazuhiro Maruyama, Asymmetric Epoxidation of Simple Olefins by Chiral Bitetralin-Linked "Twin-Coronet" Porphyrin Catalysts. Bulletin of the Chemical Society of Japan. ,vol. 66, pp. 158- 166 ,(1993) , 10.1246/BCSJ.66.158