Disodium hexahydrophthalate salt compositions and nucleated polymers comprising such compositions

作者: Darinl L. Dotson

DOI:

关键词: Organic chemistryScavengerSalt (chemistry)Flexural modulusSodium benzoatePolymerCalcium stearateMaterials scienceCalciumCrystallization

摘要: Compositions comprising specific disodium hexahydrophthalate(HHPA) salts in combination with acid scavengers (such as organic calcium or dihydrotalcite complexes) that provide highly desirable and effective nucleating properties within polymer articles polyolefins) are provided. Surprisingly, such a of HHPA salt scavenger provides high crystallization temperatures, low haze, and/or flexural modulus to the finished product. Other sodium nucleators benzoate) deleteriously react characteristically temperatures drastically reduced when stearate). Also, benzoate combined produce extremely haze levels target article, whereas inventive compositions surprisingly reduce haze. The an composition also contemplated this invention.

参考文章(8)
Wales Michael, Polymer crystallization method ,(1961)
Brian G. Morin, Jeffrey R. Jones, Martin E. Cowan, Xiaodong Edward Zhao, Brian M. Burkhart, Darin L. Dotson, Highly nucleated thermoplastic articles ,(2002)
Toshio Gensho, Masayasu Katoh, Humitaka Itoh, Toru Makino, Lubricant for plastic working ,(1995)
Markus A. Wicki, Stephen E. Amos, Chantelle Mcroberts, Kent E. Nielson, Modifying agents for polyolefins ,(1997)
H. N. Beck, Heterogeneous nucleating agents for polypropylene crystallization Journal of Applied Polymer Science. ,vol. 11, pp. 673- 685 ,(1967) , 10.1002/APP.1967.070110505
Takanori Nakashima, Yasuhiro Mochizuki, Kunio Gouda, Hirohisa Ishii, Toshiki Yamamoto, Junichiro Yokota, Shouji Kawano, Yasuhiko Nakagawa, Kazuhiro Kimura, Chikashi Okayama, Mayumi Wakata, Noriaki Saito, Masataka Sugimoto, Masami Kimura, Propylene composition, process for preparing the same, polypropylene composition, and molded articles ,(1996)
Eugene Marie Godfried Andre Van Kruchten, Carboxylates in catalytic hydrolysis of alkylene oxides ,(1999)
Pieter W O Wijga, Polymer crystallization method ,(1961)