Zirconium-based metal organic framework material and preparation method thereof
作者： Shen Mofei , Ding Tian , Liu Donghong , Wu Dan , Hu Yaqin
DOI:
关键词: High pressure 、 Zirconium 、 Preparation method 、 Crystallization 、 Repeatability 、 Reaction conditions 、 Materials science 、 Raw material 、 Metal-organic framework 、 Chemical engineering
摘要: The invention discloses a zirconium-based metal organic framework material and preparation method thereof. Plasma activated water or strongly acidic electrolyzed is added into raw system for preparing the UiO-66, crude product obtained through reaction, UiO-66 after subjected to after-treatment. According disclosed by invention, reaction temperature can be reduced 80 DEG C from 120 DEGC, time shortened within 10 minutes 24 hours, carried out in an open container, too high pressure, are not needed, repeatability good, green, high-efficiency stable synthesis realized. lowers temperature, shortens crystallization time, has advantages of simple operation, mild conditions, environment friendliness, low cost, yield like, easily implement industrial production.
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