Molecular interactions in high conductive gel electrolytes based on low molecular weight gelator.

摘要: Abstract Organic ionic gel (OIG) electrolytes, also known as electrolytes or ionogels are one example of modern functional materials with the potential to use in wide range electrochemical applications. The functionality OIGs arises from thermally reversible solidification liquids and their superior conductivity. To understand predict properties these systems it is important get knowledge about interactions on molecular level between solid gelator matrix electrolyte solution. This paper reports spectroscopic studies (FT-IR, UV–Vis Raman) based low weight methyl-4,6-O-(p-nitrobenzylidene)-α- d -glucopyranoside solution quaternary ammonium salt, tetramethylammonium bromide. process was sol-gel technique. Below characteristic temperature, defined sol phase transition T gs , samples were solid-like showed high conductivity values same order observed for pure liquid electrolytes. investigations performed a molar concentrations