Effects of NOx, SO2 and RH on the SOA formation from cyclohexene photooxidation.
作者： Chen Lv , Lin Du , Shijie Liu , Xiaotong Jiang , Narcisse T. Tsona
DOI: 10.1016/J.CHEMOSPHERE.2018.10.180
关键词: Sulfate 、 Analytical chemistry 、 Mass spectrometry 、 Chemistry 、 Cyclohexene 、 Yield (chemistry) 、 Chemical composition 、 NOx 、 Electrospray ionization 、 Relative humidity
摘要: Abstract We performed a laboratory investigation of the secondary organic aerosol (SOA) formation from cyclohexene photooxidation with different initial NOx and SO2 concentrations at low high relative humidity (RH). Both SOA yield number concentration first increase drastically then, decreased when [VOC]0/[NOx]0 ratio changed 30 to 10 3. Though presence could concentration, only under [VOC]0/[NOx]0 = 10 RH, [VOC]0/[NOx]0 = 3 RH experimental conditions, while decreasing conditions. In SO2, conditions were keys efficient sulfate promote formation. The chemical composition was characterized using hybrid quadrupole-orbitrap mass spectrometer equipped electrospray ionization (ESI-Q-Orbitrap-HRMS), few organosulfates identified. A visible enhancement molecular weight compounds observed this seemed be reason for RH.
harvard.edu
sci-hub.se 参考文章(112)
Bin Yu Kuang, Peng Lin, Min Hu, Jian Zhen Yu, Aerosol size distribution characteristics of organosulfates in the Pearl River Delta region, China Atmospheric Environment. ,vol. 130, pp. 23- 35 ,(2016) , 10.1016/J.ATMOSENV.2015.09.024
Jeff Peischl, Bruce E. Anderson, Luke D. Ziemba, Donald R. Blake, Simone Meinardi, Glenn Diskin, Jin Liao, Karl D. Froyd, Daniel M. Murphy, Frank N. Keutsch, Ge Yu, Paul O. Wennberg, Jason M. St. Clair, John D. Crounse, Armin Wisthaler, Tomas Mikoviny, Jose L. Jimenez, Pedro Campuzano‐Jost, Douglas A. Day, Weiwei Hu, Thomas B. Ryerson, Ilana B. Pollack, Airborne measurements of organosulfates over the continental U.S. Journal of Geophysical Research. ,vol. 120, pp. 2990- 3005 ,(2015) , 10.1002/2014JD022378
Barbara Nozière, Sanna Ekström, Tomas Alsberg, Sara Holmström, None, Radical‐initiated formation of organosulfates and surfactants in atmospheric aerosols Geophysical Research Letters. ,vol. 37, ,(2010) , 10.1029/2009GL041683
A. R. Attwood, R. A. Washenfelder, C. A. Brock, W. Hu, K. Baumann, P. Campuzano-Jost, D. A. Day, E. S. Edgerton, D. M. Murphy, B. B. Palm, A. McComiskey, N. L. Wagner, S. S. de Sá, A. Ortega, S. T. Martin, J. L. Jimenez, S. S. Brown, Trends in sulfate and organic aerosol mass in the Southeast U.S.: Impact on aerosol optical depth and radiative forcing Geophysical Research Letters. ,vol. 41, pp. 7701- 7709 ,(2014) , 10.1002/2014GL061669
X. K. Wang, S. Rossignol, Y. Ma, L. Yao, M. Y. Wang, J. M. Chen, C. George, L. Wang, Identification of particulate organosulfates in three megacities at the middle and lower reaches of the Yangtze River Atmospheric Chemistry and Physics. ,vol. 15, pp. 21415- 21448 ,(2015) , 10.5194/ACPD-15-21415-2015
Yadian Gómez-González, Jason D. Surratt, Filip Cuyckens, Rafal Szmigielski, Reinhilde Vermeylen, Mohammed Jaoui, Michael Lewandowski, John H. Offenberg, Tadeusz E. Kleindienst, Edward O. Edney, Frank Blockhuys, Christian Van Alsenoy, Willy Maenhaut, Magda Claeys, Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(-) electrospray ionization mass spectrometry Journal of Mass Spectrometry. ,vol. 43, pp. 371- 382 ,(2008) , 10.1002/JMS.1329
J. D. Surratt, A. W. H. Chan, N. C. Eddingsaas, M. Chan, C. L. Loza, A. J. Kwan, S. P. Hersey, R. C. Flagan, P. O. Wennberg, J. H. Seinfeld, Reactive intermediates revealed in secondary organic aerosol formation from isoprene Proceedings of the National Academy of Sciences of the United States of America. ,vol. 107, pp. 6640- 6645 ,(2010) , 10.1073/PNAS.0911114107
John J. Orlando, Geoffrey S. Tyndall, Laboratory studies of organic peroxy radical chemistry: an overview with emphasis on recent issues of atmospheric significance Chemical Society Reviews. ,vol. 41, pp. 6294- 6317 ,(2012) , 10.1039/C2CS35166H
M. D. Keywood, J. H. Kroll, V. Varutbangkul, R. Bahreini, R. C. Flagan, J. H. Seinfeld, Secondary Organic Aerosol Formation from Cyclohexene Ozonolysis: Effect of OH Scavenger and the Role of Radical Chemistry Environmental Science & Technology. ,vol. 38, pp. 3343- 3350 ,(2004) , 10.1021/ES049725J
Jo-Yu Chin, Stuart A. Batterman, VOC composition of current motor vehicle fuels and vapors, and collinearity analyses for receptor modeling Chemosphere. ,vol. 86, pp. 951- 958 ,(2012) , 10.1016/J.CHEMOSPHERE.2011.11.017