Corrole‐Decorated Porphyrin Dendrimer and Its Selective Metallation
作者： Nikolay Semenishyn , Atif Mahammed , Zeev Gross
关键词: Synthon 、 Porphyrin 、 Corrole 、 Dendrimer 、 Metalation 、 Chemistry 、 Chelation 、 Polymer chemistry 、 Supramolecular chemistry 、 Zinc 、 Photochemistry
摘要: Utilization of 4-formylbenzaldehyde in the 2+1 approach for synthesis corroles was regulated as to lead either one-pot meso-meso′-linked dimeric corrole or a monomeric with free formyl group. The latter used synthon preparation dendritic porphyrin four corroles. different chelating properties similar macrocycles allow selective insertion zinc(II) into central and cobalt(III) peripheral
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