Time-resolved EPR study of fullerene C60 adducts at 240 GHz
作者： Marco Bortolus , Maurizio Prato , Johan van Tol , Anna Lisa Maniero
DOI: 10.1016/J.CPLETT.2004.09.060
关键词: Fullerene 、 Molecular physics 、 Population 、 Tensor 、 Spectroscopy 、 Electron paramagnetic resonance 、 Analytical chemistry 、 Spectral line 、 Spectral resolution 、 Excited state 、 Chemistry
摘要: Abstract The excited triplet states of a series fullerene C 60 mono- and bis-adducts have been studied using high-frequency (240 GHz) TR-EPR spectroscopy. simulation the spectra gave zero-field splitting parameters population ratio sublevels. Moreover, thanks to increased spectral resolution available at very high frequencies, g tensor principal values directions with respect ZFS axes were determined. effect number, position nature substituents on is discussed. For some adducts signal decay was analysed.
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