Reactivity differences between haemoglobins. Part IX. Thermodynamics of the reaction of azide ion with some animal methaemoglobins
作者： A. C. Anusiem , J. G. Beetlestone , D. H. Irvine
DOI: 10.1039/J19680001337
关键词: Chemistry 、 Enthalpy 、 Azide 、 Methemoglobin 、 Physical chemistry 、 Inorganic chemistry 、 Ph range 、 Free energies 、 Standard enthalpy of formation 、 Isoelectric point 、 Ion 、 Physical and Theoretical Chemistry
摘要: The free energies and enthalpies of formation the azide complexes pigeon, dog, guinea pig methaemoglobins have been determined as a function pH. A characteristic feature these reactions is almost exact compensation between large enthalpy entropy changes over wide pH range, bell-shaped curve describing variation ΔH with correlation shown to exist maximum isoelectric point any methaemoglobin.
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