Simple Ion Transfer at Liquid|Liquid Interfaces

作者: L. J. Sanchez Vallejo , J. M. Ovejero , R. A. Fernández , S. A. Dassie

DOI: 10.1155/2012/462197

关键词: Simple (abstract algebra)Liquid liquidStatistical physicsAnalytical chemistryIon transferMass transportInterface (Java)ChemistryITIESCharge (physics)Differential equation

摘要: The main aspects related to the charge transfer reactions occurring at interface between two immiscible electrolyte solutions (ITIES) are described. particular topics be discussed involve simple ion transfer. Focus is given on theoretical approaches, numerical simulations, and experimental methodologies. Concerning procedures, different computational simulations reviewed. conclusions drawn from most accepted models described analyzed in regard their relevance for explaining of We describe implementing approaches solving differential equations associated with mass transport These correlated selected results; usefulness designing new experiments summarized. Finally, many practical applications can envisaged regarding determination physicochemical properties, electroanalysis, drug lipophilicity, phase-transfer catalysis.

参考文章(573)
Takashi Kakiuchi, Norihiro Tsujioka, Cyclic voltammetry of ion transfer across the polarized interface between the organic molten salt and the aqueous solution Electrochemistry Communications. ,vol. 5, pp. 253- 256 ,(2003) , 10.1016/S1388-2481(03)00039-0
William L. Jorgensen, Jayaraman Chandrasekhar, Jeffry D. Madura, Roger W. Impey, Michael L. Klein, Comparison of simple potential functions for simulating liquid water The Journal of Chemical Physics. ,vol. 79, pp. 926- 935 ,(1983) , 10.1063/1.445869
Md. Aminur Rahman, Hidekazu Doe, Ion transfer of tetraalkylammonium cations at an interface between frozen aqueous solution and 1,2-dichloroethane Journal of Electroanalytical Chemistry. ,vol. 424, pp. 159- 164 ,(1997) , 10.1016/S0022-0728(96)04906-6
T.J. VanderNoot, D.J. Schiffrin, Non-linear regression of impedance data for ion transfer across liquid-liquid interfaces Electrochimica Acta. ,vol. 35, pp. 1359- 1367 ,(1990) , 10.1016/0013-4686(90)85007-A
R.A. Iglesias, S.A. Dassie, Competitive facilitated ion transfer reactions across oil ∣ water interfaces Journal of Electroanalytical Chemistry. ,vol. 533, pp. 1- 17 ,(2002) , 10.1016/S0022-0728(02)01066-5
Lubos Vrbka, Martin Mucha, Babak Minofar, Pavel Jungwirth, Eric C. Brown, Douglas J. Tobias, Propensity of soft ions for the air/water interface Current Opinion in Colloid & Interface Science. ,vol. 9, pp. 67- 73 ,(2004) , 10.1016/J.COCIS.2004.05.028
Hye Jin LEE, Carine BERIET, Hubert H. GIRAULT, Stripping Voltammetric Determination of Choline Based on Micro-Fabricated Composite Membrane Analytical Sciences. ,vol. 14, pp. 71- 77 ,(1998) , 10.2116/ANALSCI.14.71