Field-effect transistors based on self-organized molecular nanostripes.

作者: Massimiliano Cavallini , Pablo Stoliar , Jean-François Moulin , Mathieu Surin , Philippe Leclère

DOI: 10.1021/NL051685+

关键词: ChemistryField-effect transistorThin filmOrganic semiconductorCondensed matter physicsElectric currentAnalytical chemistrySemiconductorOrders of magnitude (temperature)NanostructureMonolayer

摘要: Charge transport properties in organic semiconductors depend strongly on molecular order. Here we demonstrate field-effect transistors where drain current flows through a precisely defined array of nanostripes made crystalline and highly ordered molecules. The stripes are fabricated across the channel transistor by stamp-assisted deposition from solution. As solvent evaporates, capillary forces drive solution to form menisci under stamp protrusions. solute precipitates only regions is confined once critical concentration reached self-organizes into molecularly 100-200 nm wide few monolayers high. charge mobility measured along 2 orders magnitude larger than values for spin-coated thin films.

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