Process for maintaining high level of yield of acrylonitrile and hydrogen cyanide in ammoxidation of propylene

作者: Akimitsu Morii , Toshio Nakamura , Yutaka Sasaki , Yutaka Kiyomiya , Kunio Mori

DOI:

关键词: Yield (chemistry)TelluriumAcrylonitrileChemistryAmmoxidationHydrogen cyanideInorganic chemistryOxideBMA processCatalysis

摘要: A process for conducting long-term ammoxidation of propylene in the presence a metal oxide catalyst at temperature from 300° C. to 500° produce acrylonitrile and hydrogen cyanide, wherein each (A) elemental phosphorus or compound (B) tellurium is added as regenerating agent least once reaction system accordance with progress reaction, being when yields both cyanide are reduced, chosen yield reduced unchanged increased, thereby maintain high levels cyanide.

参考文章(5)
Toshio Nakamura, Yutaka Kiyomiya, Yutaka Sasaki, Process for improving activity of tellurium containing metal oxide catalysts ,(1982)
Masanori Yamaguchi, Toshio Nakamura, Yutaka Sasaki, Yoshimi Nakamura, Yutaka Kiyomiya, Process for regeneration of iron-antimony metallic oxide catalysts ,(1983)
Hiroshi Hayami, Hitoshi Shimizu, Process for the production of aromatic nitriles ,(1977)
Nakamura Toshio, Sasaki Yutaka, Kiyomiya Yutaka, Process for ammoxidation of organic compounds ,(1982)