Optimization of salt adsorption rate in membrane capacitive deionization

作者: R. Zhao , O. Satpradit , H.H.M. Rijnaarts , P.M. Biesheuvel , A. van der Wal

DOI: 10.1016/J.WATRES.2013.01.025

关键词: MembraneElectrochemistryAdsorptionSalt (chemistry)DesalinationAnalytical chemistryCapacitive deionizationChemistryCarbonElectrode

摘要: Membrane capacitive deionization (MCDI) is a water desalination technique based on applying cell voltage between two oppositely placed porous electrodes sandwiching spacer channel that transports the to be desalinated. In MCDI, ion-exchange membranes are positioned in front of each electrode prevent co-ions from leaving region during ion adsorption, thereby enhancing salt adsorption capacity. MCDI can operated at constant (CV), or electrical current (CC). this paper, we present both experimental and theoretical results for capacity rate (both CV- CC-mode) as function adsorption/desorption time, feed concentration, current, voltage. We demonstrate how by varying parameter individually, it possible systematically optimize settings given system achieve highest average recovery.

参考文章(37)
Giorgio Micale, Lucio Rizzuti, Andrea Cipollina, Seawater desalination : conventional and renewable energy processes Springer. ,(2009)
Jae-Bong Lee, Kwang-Kyu Park, Hee-Moon Eum, Chi-Woo Lee, Desalination of a thermal power plant wastewater by membrane capacitive deionization Desalination. ,vol. 196, pp. 125- 134 ,(2006) , 10.1016/J.DESAL.2006.01.011
Ju-Young Lee, Seok-Jun Seo, Sung-Hyun Yun, Seung-Hyeon Moon, Preparation of ion exchanger layered electrodes for advanced membrane capacitive deionization (MCDI). Water Research. ,vol. 45, pp. 5375- 5380 ,(2011) , 10.1016/J.WATRES.2011.06.028
Peter H. Gleick, Making Every Drop Count. Scientific American. ,vol. 284, pp. 40- 45 ,(2001) , 10.1038/SCIENTIFICAMERICAN0201-40
Seok-Jun Seo, Hongrae Jeon, Jae Kwang Lee, Gha-Young Kim, Daewook Park, Hideo Nojima, Jaeyoung Lee, Seung-Hyeon Moon, Investigation on removal of hardness ions by capacitive deionization (CDI) for water softening applications. Water Research. ,vol. 44, pp. 2267- 2275 ,(2010) , 10.1016/J.WATRES.2009.10.020
Bill B. Arnold, George W. Murphy, STUDIES ON THE ELECTROCHEMISTRY OF CARBON AND CHEMICALLY-MODIFIED CARBON SURFACES The Journal of Physical Chemistry. ,vol. 65, pp. 135- 138 ,(1961) , 10.1021/J100819A038
H LI, Y GAO, L PAN, Y ZHANG, Y CHEN, Z SUN, Electrosorptive desalination by carbon nanotubes and nanofibres electrodes and ion-exchange membranes Water Research. ,vol. 42, pp. 4923- 4928 ,(2008) , 10.1016/J.WATRES.2008.09.026
P.M. Biesheuvel, A. van der Wal, Membrane capacitive deionization Journal of Membrane Science. ,vol. 346, pp. 256- 262 ,(2010) , 10.1016/J.MEMSCI.2009.09.043