Energy transfer between Ce3+ Gd3+ or Tb3+ in KNaSO4 microphosphor

作者: Urvashi Manik , S. C. Gedam , S. J. Dhoble

DOI: 10.1002/BIO.2953

关键词: LuminescenceSpectroscopyAnalytical chemistryPhotoluminescenceUltravioletScanning electron microscopePhosphorChemistryDopingExcitation

摘要: KNaSO4 microphosphor doped with Ce,Gd and Ce,Tb prepared by a wet chemical method was studied using X-ray diffraction (XRD), scanning electron microscopy (SEM) photoluminescence (PL) characterization. has 5-µm particle size detected SEM. KNaSO4:Ce(3+),Tb(3+) showed blue green emission (at 494 nm, 557 nm, 590 nm) of Tb(3+) due to (5)D(4)  → (7)F(J) (J = 4, 5, 6) transitions. KNaSO4:Ce(3+),Gd(3+) luminescence in the ultraviolet (UV) light region at 314 nm for an excitation 271 nm wavelength. It observed that efficient energy transfer took place from Ce(3+)  → Gd(3+)  → Tb(3+) sublattices indicating could effectively sensitize Gd(3+) or (green emission). weakened enhanced significantly KNaSO4. This paper discusses development understanding effect on KNaSO4:Ce(3+).

参考文章(25)
S. C. Gedam, S. J. Dhoble, S. V. Moharil, Luminescence in Ce3+ doped mixed sulphate fluoride phosphors [NaMgSO4F and Na3SO4F] European Physical Journal-applied Physics. ,vol. 37, pp. 73- 78 ,(2007) , 10.1051/EPJAP:2006132
R.H. Chen, S.C. Yang, Li-Ming Wang, X-ray diffraction studies of twinning in KNaSO4 and K3Na(SO4)2 crystals Journal of Physics and Chemistry of Solids. ,vol. 52, pp. 859- 864 ,(1991) , 10.1016/0022-3697(91)90005-K
S.C. Gedam, S.J. Dhoble, S.V. Moharil, Dy3+and Mn2+ emission in KMgSO4Cl phosphor Journal of Luminescence. ,vol. 124, pp. 120- 126 ,(2007) , 10.1016/J.JLUMIN.2006.02.016
B.C. Joshi, U.C. Pandey, Interaction between Tb3+ and Er3+ ions in phosphate glass Journal of Physics and Chemistry of Solids. ,vol. 50, pp. 599- 601 ,(1989) , 10.1016/0022-3697(89)90453-8
J.M.P.J. Verstegen, J.L. Sommerdijk, J.G. Verriet, Cerium and terbium luminescence in LaMgAl11O19 Journal of Luminescence. ,vol. 6, pp. 425- 431 ,(1973) , 10.1016/0022-2313(73)90010-0
S.C. Gedam, S.J. Dhoble, S.V. Moharil, Eu2+ and Ce3+ emission in sulphate based phosphors Journal of Luminescence. ,vol. 128, pp. 1- 6 ,(2008) , 10.1016/J.JLUMIN.2007.03.023
S. C. Gedam, S. J. Dhoble, S. K. Omanwar, S. V. Moharil, TL in halosulphate phosphors prepared by wet chemical method European Physical Journal-applied Physics. ,vol. 39, pp. 39- 43 ,(2007) , 10.1051/EPJAP:2007108
S J Dhoble, S C Gedam, I M Nagpure, S V Godbole, M K Bhide, Photoluminescence and thermoluminescence characteristics of KXSO4Cl?:?Eu (X = Zn or Mg) halosulfate phosphor Journal of Physics D. ,vol. 40, pp. 6039- 6043 ,(2007) , 10.1088/0022-3727/40/19/040
A.K. Agarwal, N.C. Lohani, T.C. Pant, K.C. Pant, Buildup of the acceptor emission as a result of energy transfer from Tb3+ to Sm3+ in barium borate glass Journal of Solid State Chemistry. ,vol. 54, pp. 219- 225 ,(1984) , 10.1016/0022-4596(84)90149-X