Regular growth combined with lateral etching in diamond deposited over silicon substrate by using hot filament chemical vapor deposition technique

作者: M. Ali , M. Ürgen

DOI: 10.1016/J.APSUSC.2013.02.124

关键词: Materials scienceCarbon filmDeposition (phase transition)DiamondComposite materialMaterial properties of diamondChemical vapor depositionSiliconEtching (microfabrication)Thin filmNanotechnology

摘要: Abstract Hot filament chemical vapor deposition has proved to be an attractive method for growing diamond films with good quality and higher growth rate. Diamond were produced at parameters under which, it is possible have regular combined lateral etching (RGCLE). Fracture cross-section SEM images showed that RGCLE initiated over polycrystalline film proceeded by the of consecutive steps in each crystallite, which terminated square/rectangle shaped facets. All exhibit but different type behavior. Present work discusses cyclic formation crystallites modes. may find important applications where heat absorption dissipation are key issues.

参考文章(26)
M. W. Geis, N. N. Efremow, K. E. Krohn, J. C. Twichell, T. M. Lyszczarz, R. Kalish, J. A. Greer, M. D. Tabat, A new surface electron-emission mechanism in diamond cathodes Nature. ,vol. 393, pp. 431- 435 ,(1998) , 10.1038/30900
H. Sein, W. Ahmed, M. Jackson, N. Ali, J. Gracio, Stress distribution in diamond films grown on cemented WC–Co dental burs using modified hot-filament CVD Surface & Coatings Technology. ,vol. 163, pp. 196- 202 ,(2003) , 10.1016/S0257-8972(02)00618-7
S. D. Wolter, B. R. Stoner, J. T. Glass, P. J. Ellis, D. S. Buhaenko, C. E. Jenkins, P. Southworth, Textured growth of diamond on silicon via in situ carburization and bias‐enhanced nucleation Applied Physics Letters. ,vol. 62, pp. 1215- 1217 ,(1993) , 10.1063/1.108738
J. C. ANGUS, C. C. HAYMAN, Low-Pressure, Metastable Growth of Diamond and "Diamondlike" Phases Science. ,vol. 241, pp. 913- 921 ,(1988) , 10.1126/SCIENCE.241.4868.913
Kazuhisa Miyoshi, Richard L.C. Wu, Alan Garscadden, Friction and wear of diamond and diamondlike carbon coatings Surface and Coatings Technology. ,vol. 54-55, pp. 428- 434 ,(1992) , 10.1016/S0257-8972(07)80061-2
E. Salgueiredo, F.A. Almeida, M. Amaral, A.J.S. Fernandes, F.M. Costa, R.F. Silva, F.J. Oliveira, CVD micro/nanocrystalline diamond (MCD/NCD) bilayer coated odontological drill bits Diamond and Related Materials. ,vol. 18, pp. 264- 270 ,(2009) , 10.1016/J.DIAMOND.2008.08.014
D. Das, R. N. Singh, A review of nucleation, growth and low temperature synthesis of diamond thin films International Materials Reviews. ,vol. 52, pp. 29- 64 ,(2007) , 10.1179/174328007X160245
M Ali, M Ürgen, M A Atta, Effect of surface treatment on hot-filament chemical vapour deposition grown diamond films Journal of Physics D. ,vol. 45, pp. 045301- ,(2012) , 10.1088/0022-3727/45/4/045301
S. Schwarz, C. Rottmair, J. Hirmke, S. Rosiwal, R.F. Singer, CVD-diamond single-crystal growth Journal of Crystal Growth. ,vol. 271, pp. 425- 434 ,(2004) , 10.1016/J.JCRYSGRO.2004.08.003
Jingchun Zhang, Jerry W. Zimmer, Roger T. Howe, Roya Maboudian, Characterization of boron-doped micro- and nanocrystalline diamond films deposited by wafer-scale hot filament chemical vapor deposition for MEMS applications Diamond and Related Materials. ,vol. 17, pp. 23- 28 ,(2008) , 10.1016/J.DIAMOND.2007.09.010